Citation: Hao Yanwei, Tian Rongqiang, Wu Di, Duan Zheng, Mathey François. Synthesis, Structure and Coordination Chemistry of an α-Iminophosphaferrocene[J]. Chinese Journal of Organic Chemistry, ;2018, 38(1): 277-280. doi: 10.6023/cjoc201707023 shu

Synthesis, Structure and Coordination Chemistry of an α-Iminophosphaferrocene

Hao Yanwei ^a,b ,
Tian Rongqiang ^a,, ,
Wu Di ^a ,
Duan Zheng ^a,, ,
Mathey François ^a,,

a.
International Phosphorus Laboratory, International Joint Research Laboratory for Functional Organophosphorus Materials of Henan Province, College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou 450001
b.
Key Laboratory for Advanced Silicon Carbide Materials, Research Center of Functional Materials, Kaifeng University, Kaifeng 475001

Corresponding author: Tian Rongqiang, tianrq@zzu.edu.cn Duan Zheng, duanzheng@zzu.edu.cn Mathey François, frmathey@yahoo.fr
Received Date: 21 July 2017
Revised Date: 9 September 2017
Available Online: 15 January 2017
Fund Project: Project supported by the National Natural Science Foundation of China (Nos. 21302174, 21672193, 21272218), the Young Talent Research Fund of Zhengzhou University (No. 1621316006) and the Zhengzhou University of Chinathe National Natural Science Foundation of China 21302174the National Natural Science Foundation of China 21272218the Young Talent Research Fund of Zhengzhou University 1621316006the National Natural Science Foundation of China 21672193

Figures(3)

An 2-iminophospholide 1 can be obtained via two [1, 5] shifts by reaction of potassium tert-butoxide with 3, 4-di-methyl-1-phenylphosphole and an imidoyl chloride. The reaction of 1 with [Cp*FeCl]_n affords a 2-iminophosphaferrocene 2 which behaves as a P, N chelating ligand toward Mo(CO)₄ and Rh(CO)₂]⁺. The X-ray crystal structures of 2 and its Mo complex have been recorded.
- phosphaferrocene,
- imine,
- coordination chemistry
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