Citation: Sokolov Viacheslav I.. Synthesis and Application of N-Cyclopalladated Ferrocene Derivatives[J]. Chinese Journal of Organic Chemistry, ;2018, 38(1): 75-85. doi: 10.6023/cjoc201707019 shu

Synthesis and Application of N-Cyclopalladated Ferrocene Derivatives

Sokolov Viacheslav I. ^,

Institute of Organoelement Compounds, Russian Academy of Sciences, 119991 Moscow, Russian Federation

Corresponding author: Sokolov Viacheslav I., sokol@ineos.ac.ru
Received Date: 17 July 2017
Revised Date: 6 September 2017
Available Online: 29 January 2017
Fund Project: Project support by the Russian Foundation for Basic Research (No. 14-03-00467)the Russian Foundation for Basic Research 14-03-00467

Figures(22)

Progress in the synthesis and application of the cyclopalladated derivatives of ferrocene with a donor nitrogen atom in the directing group is surveyed including the planar chirality and enantioselective catalysis of organic reactions and rearrangements. Transannular palladation has been found giving achiral 1, 1'-disubstituted ferrocenes of ansa-structure. Cyclopalladated ferrocenes have been widely used as catalysts in the cross-coupling reactions (Suzuki, Heck, aza-Claisen, etc.)
- cyclopalladation,
- ferrocenyl amines,
- ferrocenyl imines,
- enantioselectivity,
- cross-coupling reactions,
- Heck reaction,
- Suzuki reaction,
- aza-Claisen rearrangement
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沈阳化工大学材料科学与工程学院沈阳 110142