Citation: Feng Zhichao, Mao Guoliang, Wu Wei, Luo Mingjian, Liu Yang. Synthesis of Phosphine Ligands Based on 5-Amino-o-cresol and Its Application in Ethylene Oligomerization[J]. Chinese Journal of Organic Chemistry, ;2018, 38(3): 698-704. doi: 10.6023/cjoc201706010 shu

Synthesis of Phosphine Ligands Based on 5-Amino-o-cresol and Its Application in Ethylene Oligomerization

Feng Zhichao ^a ,
Mao Guoliang ^a,, ,
Wu Wei ^a ,
Luo Mingjian ^a ,
Liu Yang ^b,,

a.
Provincial Key Laboratory of Oil & Gas Chemical Technology, College of Chemistry and Chemical Engineering, Northeast Petroleum University, Daqing 163318
b.
School of Petroleum Engineering, NortheastPetroleum University, Daqing 163318

Corresponding author: Mao Guoliang, maoguoliang@nepu.edu.cn Liu Yang,
Received Date: 9 June 2017
Revised Date: 28 July 2017
Available Online: 28 March 2017
Fund Project: the Program for New Century Excellent Talents in University NCET-07-0142the National Natural Science Foundation of China 51534004Project supported by the National Natural Science Foundation of China (Nos. 51534004, U1362110), and the Program for New Century Excellent Talents in University (No. NCET-07-0142)the National Natural Science Foundation of China U1362110

Figures(1)

A phosphorus ligand containing PNP and P-O structure was synthesized by substitution reaction of 5-amino-o-cresol with chlorodiphenylphosphine and its structure was conformed. Its in situ prepared complex with Cr(acac)₃ and preformed complex with CrCl₃(THF)₃ were used as main catalysts in catalyzing ethylene oligomerization, accompanied with methylaluminoxane (MAO) as cocatalyst. The effects of solvent, temperature, pressure and Al/Cr molar ratio on the activity and selectivity of the catalyst were investigated and compared with the in situ formation of 2-aminophenol and 4-aminophenol phosphine ligands catalytic system of catalyzing ethylene oligomerization effect. The experimental results showed that the activity reached 5.91×10⁶ g/(mol·Cr·h), when the reaction was carried at 50℃ with reaction pressure of 2.5 MPa and the Al/Cr molar ratio of 700. The selectivity of 1-octene was 72.94% and the total selectivity of 1-hexene and 1-octene was 82.11%.
- 5-amino-o-cresol,
- phosphorus ligand,
- chromium catalyst,
- ethylene oligomerization,
- activity,
- selectivity
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