Citation: Yang Lu, Xu Caixia. Advances in the Catalytic Markovnikov Hydration of Alkynes toward Ketones[J]. Chinese Journal of Organic Chemistry, ;2017, 37(12): 3130-3145. doi: 10.6023/cjoc201704050 shu

Advances in the Catalytic Markovnikov Hydration of Alkynes toward Ketones

Yang Lu ,
Xu Caixia ^,

Key Laboratory for Green Processing of Chemical Engineering of Xinjiang Bingtuan, School of Chemistry and Chemical En-gineering, Shihezi University, Shihezi 832003

Corresponding author: Xu Caixia, xcxia@shzu.edu.cn
Received Date: 29 April 2017
Revised Date: 7 July 2017
Available Online: 11 December 2017
Fund Project: the Applied Basic Research Program of Bingtuan 2015AG001the High-Level Talent Scientific Research Project of Shihezi University RCZX201405Project supported by the Applied Basic Research Program of Bingtuan (No. 2015AG001) and the High-Level Talent Scientific Research Project of Shihezi University (No. RCZX201405)

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Carbonyl group is one of the important building blocks in organic synthesis. The catalytic Markovnikov hydration of alkynes is an eco-friendly reaction with 100% atom economy to construct carbonyl compounds, and is one of hot spots of organic chemistry over recent years. Research progress concerning catalytic hydration of alkynes to ketones on the view of the types of catalysts, and catalytic mechanisms are concluded. Finally, the further development and challenge of catalytic hydration of alkynes are dis-cussed.
- alkyne,
- Markovnikov hydration,
- catalytic,
- ketone,
- mechanism
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