Citation: Duanmu Dandan, Leong Pak-kin, Jiang Qibai, Yan Hong. Pd(Ⅱ)-Catalyzed Synthesis of Benzyl Benzoates via Benzyl C(sp³)-H Activation[J]. Chinese Journal of Organic Chemistry, ;2017, 37(10): 2669-2677. doi: 10.6023/cjoc201704040 shu

Pd(Ⅱ)-Catalyzed Synthesis of Benzyl Benzoates via Benzyl C(sp³)-H Activation

a.
State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093
b.
Jiangsu Yangnong Chemical Co., Ltd., Yangzhou 225009

Corresponding author: Jiang Qibai, jiangqibai@163.com Yan Hong, hyan1965@nju.edu.cn
Received Date: 24 April 2017
Revised Date: 22 June 2017
Available Online: 4 October 2017
Fund Project: the National Basic Research Program of China 2013CB922101the National Natural Science Foundation of China 21271102the National Natural Science Foundation of China 21472086Project supported by the National Basic Research Program of China (No. 2013CB922101) and the National Natural Science Foundation of China (Nos. 21271102, 21472086)

Figures(4)

An efficient Pd(Ⅱ)-catalyzed synthesis of benzyl benzoates via direct functionalization of benzyl C(sp³)-H bonds was developed. The method features a broad substrate scope. This method features high tolerance of functional groups, mild reaction condition, and high chemoselective when there are multiple active C(sp³)-H bonds. A plausible oxidative coupling mechanism was proposed on the basis of mechanistic studies.
- Pd(Ⅱ)-catalysis,
- C—H activation,
- benzyl benzoates,
- perester
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Pd(Ⅱ)-Catalyzed Synthesis of Benzyl Benzoates via Benzyl C(sp3)-H Activation

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通讯作者: 陈斌, bchen63@163.com

Pd(Ⅱ)-Catalyzed Synthesis of Benzyl Benzoates via Benzyl C(sp³)-H Activation