Citation: Yang Lei, Hu Jiena, Zeng Wang, Wu Yang, Li Xianying, Zhang Dengqing, Jin Wusong. Synthesis, Self-Assemble and Fluorescence of Pyrimidine-Contained Novel Rod-Coil Structured N^C^N-Type Divalent Platium Complexes[J]. Chinese Journal of Organic Chemistry, ;2017, 37(10): 2647-2654. doi: 10.6023/cjoc201704035 shu

Synthesis, Self-Assemble and Fluorescence of Pyrimidine-Contained Novel Rod-Coil Structured N^C^N-Type Divalent Platium Complexes

Yang Lei ^a,b ,
Hu Jiena ^b ,
Zeng Wang ^b ,
Wu Yang ^b ,
Li Xianying ^c,, ,
Zhang Dengqing ^b ,
Jin Wusong ^b,,

a.
Shanghai Chongming Environmental Monitoring Station, Shanghai 202150
b.
College of Chemistry, Chemical Engineering and Biotechnology, Donghua University, Shanghai 201620
c.
College of Environmental Science and Engineering, Donghua University, Shanghai 201620

Corresponding author: Li Xianying, seanlee@dhu.edu.cn Jin Wusong, wsjin@dhu.edu.cn
Received Date: 20 April 2017
Revised Date: 13 June 2017
Available Online: 16 October 2017
Fund Project: the Science and Technology Commission of Shanghai Municipality 16JC1401900Project supported by the Science and Technology Commission of Shanghai Municipality (No. 16JC1401900)

Figures(6)

Pyrimidine-contained novel rod-coil shaped N^C^N-type tridentate ligand 1 and its platinum(Ⅱ) complexe 1-Pt were synthesized, and their structures were characterized by NMR spectroscopy and MALDI-TOF mass spectrometry. The self-assembly and optical properties of 1-Pt were investigated with FE-SEM, UV-Vis and fluorescence spectroscopies. The result indicated that the unique rod-coil structure of 1-Pt enhanced intermolecular π-π stacking and showed excellent self-assembly performance in organic solvents which allowing for modulation of luminescence.
- pyrimidine,
- rod-coil structure,
- platinum(Ⅱ) complex,
- self-assembly,
- fluorescence
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