Citation: Yang Lei, Hu Jiena, Zeng Wang, Wu Yang, Li Xianying, Zhang Dengqing, Jin Wusong. Synthesis, Self-Assemble and Fluorescence of Pyrimidine-Contained Novel Rod-Coil Structured N^C^N-Type Divalent Platium Complexes[J]. Chinese Journal of Organic Chemistry, ;2017, 37(10): 2647-2654. doi: 10.6023/cjoc201704035 shu

Synthesis, Self-Assemble and Fluorescence of Pyrimidine-Contained Novel Rod-Coil Structured N^C^N-Type Divalent Platium Complexes

Yang Lei ^a,b ,
Hu Jiena ^b ,
Zeng Wang ^b ,
Wu Yang ^b ,
Li Xianying ^c,, ,
Zhang Dengqing ^b ,
Jin Wusong ^b,,

a.
Shanghai Chongming Environmental Monitoring Station, Shanghai 202150
b.
College of Chemistry, Chemical Engineering and Biotechnology, Donghua University, Shanghai 201620
c.
College of Environmental Science and Engineering, Donghua University, Shanghai 201620

Corresponding author: Li Xianying, seanlee@dhu.edu.cn Jin Wusong, wsjin@dhu.edu.cn
Received Date: 20 April 2017
Revised Date: 13 June 2017
Available Online: 16 October 2017
Fund Project: the Science and Technology Commission of Shanghai Municipality 16JC1401900Project supported by the Science and Technology Commission of Shanghai Municipality (No. 16JC1401900)

Figures(6)

Pyrimidine-contained novel rod-coil shaped N^C^N-type tridentate ligand 1 and its platinum(Ⅱ) complexe 1-Pt were synthesized, and their structures were characterized by NMR spectroscopy and MALDI-TOF mass spectrometry. The self-assembly and optical properties of 1-Pt were investigated with FE-SEM, UV-Vis and fluorescence spectroscopies. The result indicated that the unique rod-coil structure of 1-Pt enhanced intermolecular π-π stacking and showed excellent self-assembly performance in organic solvents which allowing for modulation of luminescence.
- pyrimidine,
- rod-coil structure,
- platinum(Ⅱ) complex,
- self-assembly,
- fluorescence
1. [1]
  Jespersen, K. K; Czerw, M.; Summa, N.; Renkema, K. B.; Achord, P. D.; Goldman, A. S. J. Am. Chem. Soc. 2002, 124, 11404. doi: 10.1021/ja012460d
2. [2]
  Bergbreiter, D. E.; Osburn, P. L.; Wilson, A.; Sink, E. M. J. Am. Chem. Soc. 2000, 122, 9058. doi: 10.1021/ja001708g
3. [3]
  Jin, W.; Li, X. C.; Wan, B. S. J. Org. Chem. 2011, 76, 484. doi: 10.1021/jo101932a
4. [4]
  Fache, F.; Schulz, E.; Tomasino, M. L.; Lemaire, M. Chem. Rev. 2000, 100, 2159. doi: 10.1021/cr9902897
5. [5]
  Colombo, A.; Fiorini, F.; Septiadi, D.; Dragonetti, C.; Nisic, F.; Valore, A.; Roberto, D.; Mauro, M.; Cola, L. D. Dalton Trans. 2015, 44, 8478. doi: 10.1039/C4DT03165B
6. [6]
  Wang, Y. F.; Shi, J. W.; Chen, J. H.; Zhu, W. G.; Baranoff, E. J. Mater. Chem. C 2015, 3, 7993. doi: 10.1039/C5TC01565K
7. [7]
  Yeung, M. C.-L.; Chu, B. W.-K.; Yam, V. W.-W. ChemistryOpen 2014, 3, 172. doi: 10.1002/open.v3.5
8. [8]
  Liu, N. J.; Wang, B. Y.; Liu, W. S.; Bu, W. F. Chem. Commun. 2011, 47, 9336. doi: 10.1039/c1cc12192h
9. [9]
  Slagt, M. Q.; Van Zwieten, D. A. P.; Moerkerk, A. J. C. M.; Gobbink, R. J. M. K.; Van Koten, G. Coord. Chem. Rev. 2004, 248, 2275. doi: 10.1016/j.ccr.2004.08.014
10. [10]
  Togni, A.; Venanzi, L. M. Angew. Chem., Int. Ed. 1994, 33, 497. doi: 10.1002/(ISSN)1521-3773
11. [11]
  Vail der Boom, M. E.; Milstein, D. Chem. Rev. 2003, 103, 1759. doi: 10.1021/cr960118r
12. [12]
  Chiu, B. K. W.; Lam, M. H. W.; Lee, D. Y. K.; Wong, W. Y. J. Organomet. Chem. 2004, 689, 2888. doi: 10.1016/j.jorganchem.2004.06.006
13. [13]
  Takenaka, K.; Minakawa, M.; Uomuni, Y. J. Am. Chem. Soc. 2005, 127, 12273. doi: 10.1021/ja052780n
14. [14]
  Fossey, J. S.; Jones, G.; Motevalli, M.; Nguyen, H. V.; Richards, C. J.; Stark, M. A.; Taylor, H. V. Tetrahedron:Asymmetry 2004, 15, 2067. doi: 10.1016/j.tetasy.2004.05.032
15. [15]
  Lee, E.; Jeong, Y.; Kim, J.; Lee, M. Macromolecules 2007, 40, 8355. doi: 10.1021/ma071511+
16. [16]
  Ryu, J.; Kim, H.; Huang, Z.; Lee, E.; Lee, M. Angew. Chem., Int. Ed. 2006, 45, 5304. doi: 10.1002/(ISSN)1521-3773
17. [17]
  Lee, E.; Huang, Z.; Ryu, J. H.; Lee, M. Chem. Eur. J. 2008, 14, 6957. doi: 10.1002/chem.v14:23
18. [18]
  Ryu, J. H.; Oh, N. K.; Lee, M. Chem. Commun. 2005, 13, 1770.
19. [19]
  Moon, K. S.; Kim, H. J.; Lee, E.; Lee, M. Angew. Chem., Int. Ed. 2007, 46, 6807. doi: 10.1002/(ISSN)1521-3773
20. [20]
  Moon, K, S.; Lee, E.; Lee, M. Chem. Commun. 2008, 26, 3061.
21. [21]
  Lee, E.; Kim, J.; Lee, M. Angew. Chem., Int. Ed. 2008, 47, 6375. doi: 10.1002/anie.v47:34
22. [22]
  Zhong, K. L.; Huang, Z. G.; Man, Z. J.; Jin, L. Y.; Yin, B. Z.; Lee, M. J. Polym. Sci. Part. A:Polym. Chem. 2010, 48, 1415. doi: 10.1002/pola.v48:6
23. [23]
  Zhong, K. L.; Man, Z. J.; Huang, Z. G.; Chen, T.; Yin, B. Z.; Jin, L. Y. Polym. Int. 2011, 60, 845. doi: 10.1002/pi.v60.5
24. [24]
  Ryu, J.; Cho, B.; Lee, M. Bull. Chem. Soc. 2006, 27, 1270. doi: 10.5012/bkcs.2006.27.9.1270
25. [25]
  Lim, Y.; Moon, K. S.; Lee, M. Chem. Soc. Rev. 2009, 38, 925. doi: 10.1039/b809741k
26. [26]
  Lee, M.; Cho, B.; Zin, W. C. Chem. Rev. 2001, 101, 3869. doi: 10.1021/cr0001131
27. [27]
  Li, X. Y.; Hu, J. N.; Wu, Y.; Li, R.; Xiao, D. D.; Zeng, W.; Zhang, D. Q.; Xiang, Y. J.; Jin, W. S. Dyes Pigm. 2017, 141, 188. doi: 10.1016/j.dyepig.2017.02.020
28. [28]
  Li, K.; Cheng, G.; Ma, C. S.; Guan, X, G.; Kwork, W. M.; Chen, Y.; Luac, W.; Che, C. M. Chem. Sci. 2013, 4, 2630. doi: 10.1039/c3sc21822h
29. [29]
  Farinola, G. M.; Ragni, R. Chem. Soc. Rev. 2011, 40, 3467 doi: 10.1039/c0cs00204f
30. [30]
  Kim, H. J.; Zin, W. C.; Lee, M. J. Am. Chem. Soc. 2004, 126, 7009. doi: 10.1021/ja049799v
31. [31]
  Xiao, D.; Zhang, D.; Chen, B.; Xie, D.; Xiang, Y.; Li, X.; Jin, W. Langmuir 2015, 31, 10649. doi: 10.1021/acs.langmuir.5b02273
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