Citation: Zhang Feng, Liu Xianghua, Liu Wei, Deng Guojun. Application of Pd-Monodentate Phosphorus Catalysts in the Asymmetric Hydrosilylation Reactions of Alkenes[J]. Chinese Journal of Organic Chemistry, ;2017, 37(10): 2555-2568. doi: 10.6023/cjoc201704011 shu

Application of Pd-Monodentate Phosphorus Catalysts in the Asymmetric Hydrosilylation Reactions of Alkenes

a.
College of Science, Hunan Agricultural University, Changsha 410128
b.
College of Chemistry, Xiangtan University, Xiangtan 411105

Corresponding author: Zhang Feng, zhang_feng0911@163.com
Received Date: 10 April 2017
Revised Date: 15 May 2017
Available Online: 7 October 2017
Fund Project: the National Natural Science Foundation of China 21302051Project supported by the National Natural Science Foundation of China (No. 21302051) and the Natural Science Foundation of Hunan Province (No. 14JJ3091)the Natural Science Foundation of Hunan Province 14JJ3091

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Asymmetric hydrosilylation of alkenes, which has been recognized as an important method for the preparations of optically active secondary alcohols, deserves widespread attention over the world. It is reported that such reaction can be catalyzed by Pd-monodentate phosphorus catalysts with excellent reactivity and enantioselectivity. In the past decades, a wide variety of chiral monodentate phosphorus ligands have been developed because of their stable structure, facile synthesis, convenient modification, unique efficiency. Among them, there are three predominant classes of ligands-phosphines based on an axially chiral biaryl scaffold, phosphines based on a planar chiral ferrocene scaffold and chiral phosphoramidites. Herein, the recent advances in asymmetric hydrosilylation of alkyl-substituted alkenes, styrene derivatives, 1, 3-dienes and other carbon-carbon double bond compounds catalyzed by palladium monodentate phosphorus catalysts are summarized. The perspective is also discussed.
- Pd catalyzed,
- monodentate phosphorus ligands,
- alkenes,
- asymmetric hydrosilylation
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