Citation: Huang Yulin, Chen Qian. Fluorination Reaction of P(Ⅲ) Compounds with the Electrophilic Fluorinating Reagent Selectfluor[J]. Chinese Journal of Organic Chemistry, ;2017, 37(10): 2745-2751. doi: 10.6023/cjoc201704001 shu

Fluorination Reaction of P(Ⅲ) Compounds with the Electrophilic Fluorinating Reagent Selectfluor

Huang Yulin ^a ,
Chen Qian ^a,b,,

a.
School of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou 510006
b.
Key Laboratory of Functional Molecular Engineering of Guangdong Province, South China University of Technology, Guangzhou 510640

Corresponding author: Chen Qian, qianchen@gdut.edu.cn
Received Date: 1 April 2017
Revised Date: 10 May 2017
Available Online: 2 October 2017
Fund Project: Project supported by the Science and Technology Planning Project of Guangdong Province (No.2015A020211026), the 100 Young Talents Program of Guangdong University of Technology (No.220413506) and the Open Fund of the Key Laboratory of Functional Molecular Engineering of Guangdong Province (No.2016kf07)the 100 Young Talents Program of Guangdong University of Technology 220413506the Science and Technology Planning Project of Guangdong Province 2015A020211026the Open Fund of the Key Laboratory of Functional Molecular Engineering of Guangdong Province 2016kf07

Figures(2)

A fluorination reaction of P(Ⅲ) compounds with the electrophilic fluorinating reagent Selectfluor is described. The reaction proceeded in acetonitrile/water at room temperature for 15~60 min to afford phosphoric fluorides in 34%~81% yields.
- P(Ⅲ) compound,
- electrophilic fluorinating reagent,
- fluorination reaction,
- phosphoric fluoride
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