Citation: Li Yinwu, Zhang Jianyu, Shu Siwei, Shao Youxiang, Liu Yan, Ke Zhuofeng. Boron-Based Lewis Acid Transition Metal Complexes as Potential Bifunctional Catalysts[J]. Chinese Journal of Organic Chemistry, ;2017, 37(9): 2187-2202. doi: 10.6023/cjoc201703002 shu

Boron-Based Lewis Acid Transition Metal Complexes as Potential Bifunctional Catalysts

Li Yinwu ^a ,
Zhang Jianyu ^a ,
Shu Siwei ^b ,
Shao Youxiang ^a ,
Liu Yan ^b,, ,
Ke Zhuofeng ^a,,

a.
Key Laboratory for Polymeric Composite & Functional Materials of Ministry of Education, School of Materials Science & Engineering, Sun Yat-sen University, Guangzhou 510275
b.
School of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou 510006

Corresponding author: Liu Yan, yanliu@gdut.edu.cn Ke Zhuofeng, kezhf3@mail.sysu.edu.cn
Received Date: 1 March 2017
Revised Date: 27 May 2017
Available Online: 14 September 2017
Fund Project: the National Natural Science Foundation of China 21502023the Guangdong Natural Science Funds for Distinguished Young Scholar 2015A030306027Project supported by the National Natural Science Foundation of China (Nos. 21673301, 21473261, 21502023) and the Guangdong Natural Science Funds for Distinguished Young Scholar (No. 2015A030306027)the National Natural Science Foundation of China 21673301the National Natural Science Foundation of China 21473261

Figures(37)

Lewis acid-transition metal (LA-TM) complexes, with the LA site functions as an electron acceptor and the TM center functions as an electron donor, have been emerging as a new type of bifunctional catalysts lately, different from traditional transition metal bifunctional catalysts. Due to their rapid developments recently, the boron-based LA-TM complexes, which are divided into three major types, the sp³, sp², and sp boron-based complexes, are reviewed in this paper according to their binding features. Reactions promoted by this new type of LA-TM bifunctional catalysts have been surveyed, including migration reactions, activation of H-H/E-H/E-E bonds, hydrogenations, hydrosilylations, and transfer dehydrogenation reactions etc. This overview of boron-based LA-TM complexes could provide valuable information to explore the new horizon in LA-TM bifunctional catalysis.
- Lewis acid,
- transition metal,
- bifunctional catalysis,
- boron,
- activation,
- hydrogenation,
- dehydrogenation
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沈阳化工大学材料科学与工程学院沈阳 110142