Citation: Yang Jia, Xiao Jing, Zhou Yongbo, Chen Tieqiao, Yin Shuangfeng, Han Libiao. Recent Advances in the Synthesis of Organophosphorus Compounds via Cross Coupling between Readily Available Materials and P-H Compounds[J]. Chinese Journal of Organic Chemistry, ;2017, 37(5): 1055-1068. doi: 10.6023/cjoc201702050 shu

Recent Advances in the Synthesis of Organophosphorus Compounds via Cross Coupling between Readily Available Materials and P-H Compounds

Yang Jia ^a ,
Xiao Jing ^a,c ,
Zhou Yongbo ^a,*,, ,
Chen Tieqiao ^a ,
Yin Shuangfeng ^a ,
Han Libiao ^b,*,,

a.
State Key Laboratory of Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082
b.
National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba, Ibaraki 305-8565, Japan
c.
Key Laboratory of Theoretical Organic Chemistry and Functional Molecule of the Ministry of Education, Hunan University of Science and Technology, Xiangtan 411201

Corresponding author: Zhou Yongbo, zhouyb@hnu.edu.cn Han Libiao, libiao-han@aist.go.jp
Received Date: 28 February 2017
Revised Date: 8 April 2017

Fund Project: the National Natural Science Foundation of China 21273066the National Natural Science Foundation of China 21573065the National Natural Science Foundation of China Nos. 21373080the Natural Science Foundation of Hunan Province No. 2016JJ1007

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This mini-review focuses on the recent advances in the synthesis of organophosphorus compounds via cross coupling of P-H compounds with readily available starting materials, mainly including the reactions of terminal alkynes and heteroatom compounds (oxygen, sulfur or nitrogen-contained compounds) with P-H compounds forming sp-C-P, sp²-C-P, sp³-C-P, and P-Z bonds. Related reaction mechanisms are also discussed.
- P-H compounds,
- cross coupling,
- organophosphorus compounds
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