Citation: Luan Huaxin, Sun Hongjian, Xue Benjing, Li Xiaoyan. Synthesis and Properties of a Se-Coordinated Hydrido Cobalt(Ⅲ) Complex Supported by Trimethylphosphine[J]. Chinese Journal of Organic Chemistry, ;2017, 37(6): 1392-1397. doi: 10.6023/cjoc201702047 shu

Synthesis and Properties of a Se-Coordinated Hydrido Cobalt(Ⅲ) Complex Supported by Trimethylphosphine

Key Laboratory of Special Functional Aggregated Materials, Ministry of Education, School of Chemistry and Chemical Engineering, Shandong University, Jinan 250199

Corresponding author: Li Xiaoyan, xli63@sdu.edu.cn
Received Date: 28 February 2017
Revised Date: 14 April 2017

Fund Project: the National Natural Science Foundation of China 21372143

Figures(5)

A mononuclear cobalt(Ⅱ) complex[Co(4-MeOC₆H₄Se)₂(PMe₃)₃] (1) and a dinuclear cobalt diphenylselenolato complex[Co(PMe₃)₂(SeC₆H₄-2-Me)]₂ (2) were obtained from the reaction of 4-methoxyselenophenol and 2-methylseleno-phenol with Co(PMe₃)₄, respectively. The dicarbonyl cobalt(Ⅰ) complex[Co(PMe₃)₂(CO)₂(SeC₆H₄-2-Me)] (3) was formed through the reaction of complex 2 with carbon monoxide. A novel selenophenolato hydridocobalt(Ⅲ) complex[mer-Co(H)(SePh)₂(PMe₃)₃] (4) and a dinuclear cobalt diphenylselenolato complex[Co(PMe₃)₂(SePh)]₂ (5) were synthesized by the reaction of selenophenol with Co(PMe₃)₄. It was found that complex 4 could catalyze the hydrosilylation of aldehydes and ketones. The molecular structures of 1, 3 and 4 were determined by X-ray diffraction.
- hydrido cobalt complex,
- selenophenol,
- Se-coordinated,
- hydrosilylation,
- carbonyl cobalt complex
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