Citation: Luan Huaxin, Sun Hongjian, Xue Benjing, Li Xiaoyan. Synthesis and Properties of a Se-Coordinated Hydrido Cobalt(Ⅲ) Complex Supported by Trimethylphosphine[J]. Chinese Journal of Organic Chemistry, ;2017, 37(6): 1392-1397. doi: 10.6023/cjoc201702047 shu

Synthesis and Properties of a Se-Coordinated Hydrido Cobalt(Ⅲ) Complex Supported by Trimethylphosphine

Key Laboratory of Special Functional Aggregated Materials, Ministry of Education, School of Chemistry and Chemical Engineering, Shandong University, Jinan 250199

Corresponding author: Li Xiaoyan, xli63@sdu.edu.cn
Received Date: 28 February 2017
Revised Date: 14 April 2017

Fund Project: the National Natural Science Foundation of China 21372143

Figures(5)

A mononuclear cobalt(Ⅱ) complex[Co(4-MeOC₆H₄Se)₂(PMe₃)₃] (1) and a dinuclear cobalt diphenylselenolato complex[Co(PMe₃)₂(SeC₆H₄-2-Me)]₂ (2) were obtained from the reaction of 4-methoxyselenophenol and 2-methylseleno-phenol with Co(PMe₃)₄, respectively. The dicarbonyl cobalt(Ⅰ) complex[Co(PMe₃)₂(CO)₂(SeC₆H₄-2-Me)] (3) was formed through the reaction of complex 2 with carbon monoxide. A novel selenophenolato hydridocobalt(Ⅲ) complex[mer-Co(H)(SePh)₂(PMe₃)₃] (4) and a dinuclear cobalt diphenylselenolato complex[Co(PMe₃)₂(SePh)]₂ (5) were synthesized by the reaction of selenophenol with Co(PMe₃)₄. It was found that complex 4 could catalyze the hydrosilylation of aldehydes and ketones. The molecular structures of 1, 3 and 4 were determined by X-ray diffraction.
- hydrido cobalt complex,
- selenophenol,
- Se-coordinated,
- hydrosilylation,
- carbonyl cobalt complex
1. [1]
  Bauer, I.; Knölker, H. J. Chem. Rev. 2015, 115, 3170. doi: 10.1021/cr500425u
2. [2]
  Wang, W. H.; Himeda, Y.; Muckerman, J. T.; Manbeck, G. F.; Fujita, E. Chem. Rev. 2015, 115, 12936. doi: 10.1021/acs.chemrev.5b00197
3. [3]
  Eberhardt, N. A.; Guan, H. R. Chem. Rev. 2016, 116, 8373. doi: 10.1021/acs.chemrev.6b00259
4. [4]
  Guo, N.; Zhu, S. F. Chin. J. Org. Chem. 2015, 35, 1383 (in Chinese).
5. [5]
  Yuan, Q. J.; Zhang, W. B. Chin. J. Org. Chem. 2015, 36, 274 (in Chinese).
6. [6]
  Zhang, H.; Sun, H. J.; Li, X. Y. Chin. J. Org. Chem. 2016, 36, 2843 (in Chinese).
7. [7]
  Gunanathan, C.; Hölscher, M.; Pan, F.; Leitner, W. J. Am. Chem. Soc. 2012, 134, 14349. doi: 10.1021/ja307233p
8. [8]
  Jiang, Y.; Huang, W.; Schmalle, H. W.; Blacque, O.; Fox, T.; Berke, H. Organometallics 2013, 32, 7043. doi: 10.1021/om400733u
9. [9]
  Dai, N.; Shang, R.; Fu, M. C.; Fu, Y. Chin. J. Chem. 2015, 33, 405. doi: 10.1002/cjoc.v33.4
10. [10]
  Liang, M. T.; Xia, X. F.; Liu, X.; Li, H. X. Chin. J. Chem. 2015, 33, 578. doi: 10.1002/cjoc.201500072
11. [11]
  Yang, X. ACS Catal. 2012, 2, 964. doi: 10.1021/cs3000683
12. [12]
  Huff, C. A.; Sanford, M. S. ACS Catal. 2013, 3, 2412. doi: 10.1021/cs400609u
13. [13]
  Hu, P.; Diskin-Posner, Y.; Ben-David, Y.; Milstein, D. ACS Catal. 2014, 4, 2649. doi: 10.1021/cs500937f
14. [14]
  Arndtsen, B. A.; Bergman, R. G. Science 1995, 270, 1970. doi: 10.1126/science.270.5244.1970
15. [15]
  Li, C.; Widjaja, E.; Garland, M. Organometallics 2004, 23, 4131. doi: 10.1021/om0342661
16. [16]
  Filonenko, G. A.; Hensen, E. J.; Pidko, E. A. Catal. Sci. Technol. 2014, 4, 3474. doi: 10.1039/C4CY00568F
17. [17]
  McGrady, G. S.; Guilera, G. Chem. Soc. Rev. 2003, 32, 383. doi: 10.1039/b207999m
18. [18]
  Conifer, C.; Gunanathan, C.; Rinesch, T.; Hölscher, M.; Leitner, W. Eur. J. Inorg. Chem. 2015, 333.
19. [19]
  Chen, H.; Schlecht, S.; Semple, T. C.; Hartwig, J. F. Science 2000, 287, 1995. doi: 10.1126/science.287.5460.1995
20. [20]
  Hauwert, P.; Boerleider, R.; Warsink, S.; Weigand, J. J.; Elsevier, C. J. J. Am. Chem. Soc. 2010, 132, 16900. doi: 10.1021/ja1062407
21. [21]
  Fan, L.; Parkin, S.; Ozerov, O. V. J. Am. Chem. Soc. 2005, 127, 16772. doi: 10.1021/ja0557637
22. [22]
  Lersch, M.; Tilset, M. Chem. Rev. 2005, 105, 2471. doi: 10.1021/cr030710y
23. [23]
  Haenel, M. W.; Oevers, S.; Angermund, K.; Kaska, W. C.; Fan, H. J.; Hall, M. B. Angew. Chem. 2001, 113, 3708. doi: 10.1002/(ISSN)1521-3757
24. [24]
  Nielsen, M.; Alberico, E.; Baumann, W.; Drexler, H. J.; Junge, H.; Gladiali, S.; Beller, M. Nature 2013, 495, 85. doi: 10.1038/nature11891
25. [25]
  Clarke, Z. E.; Maragh, P. T.; Dasgupta, T. P.; Gusev, D. G.; Lough, A. J.; Abdur-Rashid, K. Organometallics 2006, 25, 4113. doi: 10.1021/om060049z
26. [26]
  Jiang, Y.; Blacque, O.; Fox, T.; Frech, C. M.; Berke, H. Organo-metallics 2009, 28, 5493. doi: 10.1021/om900458e
27. [27]
  Guo, R.; Lough, A. J.; Morris, R. H.; Song, D. Organometallics 2004, 23, 5524. doi: 10.1021/om049460h
28. [28]
  Burling, S.; Kociok-Köhn, G.; Mahon, M. F.; Whittlesey, M. K.; Williams, J. M. Organometallics 2005, 24, 5868. doi: 10.1021/om050600c
29. [29]
  Jones, W. D. Inorg. Chem. 2005, 44, 4475. doi: 10.1021/ic050007n
30. [30]
  Fu, X.; Wayland, B. B. J. Am. Chem. Soc. 2005, 127, 16460. doi: 10.1021/ja054548n
31. [31]
  Li, X.; Chianese, A. R.; Vogel, T.; Crabtree, R. H. Org. Lett. 2005, 7, 5437. doi: 10.1021/ol052186i
32. [32]
  Ding, K.; Brennessel, W. W.; Holland, P. L. J. Am. Chem. Soc. 2009, 131, 10804. doi: 10.1021/ja902812y
33. [33]
  Du, J. Z.; Wang, L. B.; Xie, M. H.; Deng, L. Angew. Chem., Int. Ed. 2015, 54, 12640. doi: 10.1002/anie.201505937
34. [34]
  Sun, J.; Luo, L.; Luo, Y.; Deng, L. Angew. Chem., Int. Ed. 2017, 56, 2720. doi: 10.1002/anie.v56.10
35. [35]
  Scheuermann, M. L.; Semproni, S. P.; Pappas, I.; Chirik, P. J. Inorg. Chem. 2014, 53, 9463. doi: 10.1021/ic501901n
36. [36]
  Tokmic, K.; Markus, C. R.; Zhu, L.; Fout, A. R. J. Am. Chem. Soc. 2016, 138, 11907. doi: 10.1021/jacs.6b07066
37. [37]
  Jeletic, M. S.; Helm, M. L.; Hulley, E. B.; Mock, M. T.; Appel, A. M.; Linehan, J. C. ACS Catal. 2014, 4, 3755. doi: 10.1021/cs5009927
38. [38]
  Yu, R. P.; Darmon, J. M.; Milsmann, C.; Margulieux, G. W.; Stieber, S. C. E.; DeBeer, S.; Chirik, P. J. J. Am. Chem. Soc. 2013, 135, 13168. doi: 10.1021/ja406608u
39. [39]
  Niu, Q.; Sun, H.; Li, X.; Klein, H.-F.; Flörke, U. Organometallics 2013, 32, 5235. doi: 10.1021/om4005687
40. [40]
  Zhou, H.; Sun, H.; Zhang, S.; Li, X. Organometallics 2015, 34, 1479. doi: 10.1021/om5011929
41. [41]
  Xiong, Z.; Li, X.; Zhang, S.; Shi, Y.; Sun, H. Organometallics 2016, 35, 357. doi: 10.1021/acs.organomet.5b00937
42. [42]
  Jiao, G.; Li, X.; Sun, H.; Xu, X. J. Organomet. Chem. 2007, 692, 4251. doi: 10.1016/j.jorganchem.2007.06.031
43. [43]
  Foster, D. G. Org. Synth. 1944, 24, 89. doi: 10.15227/orgsyn.024.0089
44. [44]
  Klein, H.-F.; Karsch, H. H. Chem. Ber. 1975, 108, 944. doi: 10.1002/(ISSN)1099-0682
45. [45]
  Dolomanov, O. V.; Bourhis, L. J.; Gildea, R. J.; Howard, J. A. K.; Puschmann, H. J. Appl. Crystallogr. 2009, 42, 339. doi: 10.1107/S0021889808042726
46. [46]
  Sheldrick, G. M. Acta Crystallogr. 2008, A64, 112.
47. [47]
  Sheldrick, G. M. Acta Crystallogr. 2015, C71, 3.
1. [1]
  Jiaxun Wu , Mingde Li , Li Dang . The R eaction of Metal Selenium Complexes with Olefins as a Tutorial Case Study for Analyzing Molecular Orbital Interaction Modes. University Chemistry, 2025, 40(3): 108-115. doi: 10.12461/PKU.DXHX202405098
2. [2]
  Cunling Ye , Xitong Zhao , Hongfang Wang , Zhike Wang . A Formula for the Calculation of Complex Concentrations Arising from Side Reactions and Its Applications. University Chemistry, 2024, 39(4): 382-386. doi: 10.3866/PKU.DXHX202310043
3. [3]
  Linjie ZHU , Xufeng LIU . Electrocatalytic hydrogen evolution performance of tetra-iron complexes with bridging diphosphine ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 321-328. doi: 10.11862/CJIC.20240207
4. [4]
  Ke QIAO , Yanlin LI , Shengli HUANG , Guoyu YANG . Advancements in asymmetric catalysis employing chiral iridium (ruthenium) complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2091-2104. doi: 10.11862/CJIC.20240265
5. [5]
  Shiyi WANG , Chaolong CHEN , Xiangjian KONG , Lansun ZHENG , Lasheng LONG . Polynuclear lanthanide compound [Ce₄^ⅢCe₆^Ⅳ(μ₃-O)₄(μ₄-O)₄(acac)₁₄(CH₃O)₆]·2CH₃OH for the hydroboration of amides to amine. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 88-96. doi: 10.11862/CJIC.20240342
6. [6]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
7. [7]
  Xiaowei TANG , Shiquan XIAO , Jingwen SUN , Yu ZHU , Xiaoting CHEN , Haiyan ZHANG . A zinc complex for the detection of anthrax biomarker. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1850-1860. doi: 10.11862/CJIC.20240173
8. [8]
  Zhuoming Liang , Ming Chen , Zhiwen Zheng , Kai Chen . Multidimensional Studies on Ketone-Enol Tautomerism of 1,3-Diketones By ¹H NMR. University Chemistry, 2024, 39(7): 361-367. doi: 10.3866/PKU.DXHX202311029
9. [9]
  Qilu DU , Li ZHAO , Peng NIE , Bo XU . Synthesis and characterization of osmium-germyl complexes stabilized by triphenyl ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1088-1094. doi: 10.11862/CJIC.20240006
10. [10]
  Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two Ln^Ⅲ₃ complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
11. [11]
  Wei Li , Ze Chang , Meihui Yu , Ying Zhang . Curriculum Ideological and Political Design of Piezoelectricity Measurement Experiments of Coordination Compounds. University Chemistry, 2024, 39(2): 77-82. doi: 10.3866/PKU.DXHX202308004
12. [12]
  Ji Qi , Jianan Zhu , Yanxu Zhang , Jiahao Yang , Chunting Zhang . Visible Color Change of Copper (II) Complexes in Reversible SCSC Transformation: The Effect of Structure on Color. University Chemistry, 2024, 39(3): 43-57. doi: 10.3866/PKU.DXHX202307050
13. [13]
  Keweiyang Zhang , Zihan Fan , Liyuan Xiao , Haitao Long , Jing Jing . Unveiling Crystal Field Theory: Preparation, Characterization, and Performance Assessment of Nickel Macrocyclic Complexes. University Chemistry, 2024, 39(5): 163-171. doi: 10.3866/PKU.DXHX202310084
14. [14]
  Tianyun Chen , Ruilin Xiao , Xinsheng Gu , Yunyi Shao , Qiujun Lu . Synthesis, Crystal Structure, and Mechanoluminescence Properties of Lanthanide-Based Organometallic Complexes. University Chemistry, 2024, 39(5): 363-370. doi: 10.3866/PKU.DXHX202312017
15. [15]
  Wenjing ZHANG , Xiaoqing WANG , Zhipeng LIU . Recent developments of inorganic metal complex-based photothermal materials and their applications in photothermal therapy. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2356-2372. doi: 10.11862/CJIC.20240254
16. [16]
  Qingjun PAN , Zhongliang GONG , Yuwu ZHONG . Advances in modulation of the excited states of photofunctional iron complexes. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 45-58. doi: 10.11862/CJIC.20240365
17. [17]
  Hong Wu , Yuxi Wang , Hongyan Feng , Xiaokui Wang , Bangkun Jin , Xuan Lei , Qianghua Wu , Hongchun Li . Application of Computational Chemistry in the Determination of Magnetic Susceptibility of Metal Complexes. University Chemistry, 2025, 40(3): 116-123. doi: 10.12461/PKU.DXHX202405141
18. [18]
  Yan LIU , Jiaxin GUO , Song YANG , Shixian XU , Yanyan YANG , Zhongliang YU , Xiaogang HAO . Exclusionary recovery of phosphate anions with low concentration from wastewater using a CoNi-layered double hydroxide/graphene electronically controlled separation film. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1775-1783. doi: 10.11862/CJIC.20240043
19. [19]
  Zhicheng JU , Wenxuan FU , Baoyan WANG , Ao LUO , Jiangmin JIANG , Yueli SHI , Yongli CUI . MOF-derived nickel-cobalt bimetallic sulfide microspheres coated by carbon: Preparation and long cycling performance for sodium storage. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 661-674. doi: 10.11862/CJIC.20240363
20. [20]
  Fei Liu , Dong-Yang Zhao , Kai Sun , Ting-Ting Yu , Xin Wang . Comprehensive Experimental Design for Photochemical Synthesis, Analysis, and Characterization of Seleno-Containing Medium-Sized N-Heterocycles. University Chemistry, 2024, 39(3): 369-375. doi: 10.3866/PKU.DXHX202309047

Get Citation

PDF

XML

Metrics

PDF Downloads(5)
Abstract views(1359)
HTML views(249)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142