Citation: Dong Xu, Hou Yongzheng, Meng Fanwei, Liu Hongbo, Liu Hui. Recent Advances on Alkyl-Heck Reaction[J]. Chinese Journal of Organic Chemistry, ;2017, 37(5): 1088-1098. doi: 10.6023/cjoc201702040 shu

Recent Advances on Alkyl-Heck Reaction

Dong Xu ^a,b ,
Hou Yongzheng ^a ,
Meng Fanwei ^a ,
Liu Hongbo ^a ,
Liu Hui ^a,b,*,,

a.
College of Materials Science and Engineering, Hunan University, Changsha 410082
b.
School of Chemical Engineering, Shandong University of Technology, Zibo 255049

Corresponding author: Liu Hui, huiliu1030@sdut.edu.cn
Received Date: 26 February 2017
Revised Date: 23 March 2017

Fund Project: the Special Funding for Postdoctoral Innovation Project of Shandong Province No. 201501002the China Postdoctoral Science Foundation No. 2016M590736

Figures(18)

Recently, palladium-catalyzed alkyl-Heck reaction causes more attentions due to the wide application in the construction of C(sp³)-C(sp²). This review gives an up-to-date overview of alkyl-Heck reaction involving palladium radical intermediates, which are sorted in two categories of intramolecular reactions and intermolecular reactions. For most of these transformations, the plausible mechanisms are demonstrated in details. Clarification of these issues is the key point for understanding the palladium radical involved alkyl-Heck reactions and developing new high performance methodologies.
- Pd-catalyzed,
- radical,
- Heck reaction,
- alkyl halide
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