Citation: Zheng Nan, Song Wangze. Progress on Transition Metal-Catalyzed Asymmetric Allylic Alkylation Reaction of 1, 3-Dicarbonyl Compounds[J]. Chinese Journal of Organic Chemistry, ;2017, 37(5): 1099-1110. doi: 10.6023/cjoc201702013 shu

Progress on Transition Metal-Catalyzed Asymmetric Allylic Alkylation Reaction of 1, 3-Dicarbonyl Compounds

Zheng Nan ^a,c ,
Song Wangze ^b,c,*,,

a.
School of Chemical Engineering, Dalian University of Technology, Dalian 116024
b.
School of Pharmaceutical Science and Technology, Dalian University of Technology, Dalian 116024
c.
State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116024

Corresponding author: Song Wangze, wzsong@dlut.edu.cn
Received Date: 12 February 2017
Revised Date: 13 March 2017

Fund Project: the Fundamental Research Funds for the Central Universities No. DUT16RC(3)070

Figures(14)

Asymmetric allylic alkylation reaction of 1, 3-dicarbonyl compounds is one of the most important methods for forming chiral carbon center. This review summarizes the progress on transition metal-catalyzed asymmetric allylic alkylation reaction of 1, 3-dicarbonyl compounds. Different allylating reagents such as allylic esters, allylic alcohols, allylic halides, olefins, allenes and others for the synthesis of α-allyl substituted 1, 3-dicarbonyl compounds are discussed.
- transition-metal catalysis,
- 1, 3-dicarbonyl compounds,
- asymmetric allylic alkylation reaction
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