Citation: Liu Yunyun, Xiong Jin, Wei Li. Recent Advances in the C(sp²)-S Bond Formation Reactions by Transition Metal-Free C(sp²)-H Functionalization[J]. Chinese Journal of Organic Chemistry, ;2017, 37(7): 1667-1680. doi: 10.6023/cjoc201702009 shu

Recent Advances in the C(sp²)-S Bond Formation Reactions by Transition Metal-Free C(sp²)-H Functionalization

College of Chemistry and Chemical Engineering, Jiangxi Normal University, Nanchang 330022

Corresponding author: Liu Yunyun, chemliuyunyun@jxnu.edu.cn
Received Date: 9 February 2017
Revised Date: 16 March 2017
Available Online: 1 July 2017
Fund Project: the National Natural Science Foundation of China 21562024Project supported by the National Natural Science Foundation of China (No. 21562024)

Figures(31)

Aryl/vinyl thioethers containing C(sp²)-S bonds are prevalent in biologically relevant molecules and compounds with other potential applications. Around the past decade, rapid progress has taken place in the research area of C(sp²)-S construction, and a large number of efficient new catalytic systems as well as structurally versatile substrates have been identified for such reactions, which significantly enriched the content of the synthetic methodologies on C(sp²)-S bond formation. This review introduces mainly the research advances on transition metal-free C(sp²)-S bond forming reaction by means of C(sp²)-H bond functionalization over the period of 2001~2016.
- transition metal-free,
- C(sp²)-H bond,
- (Hetero)aryl,
- vinyl,
- C(sp²)-S bond formation
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Recent Advances in the C(sp2)-S Bond Formation Reactions by Transition Metal-Free C(sp2)-H Functionalization

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Recent Advances in the C(sp²)-S Bond Formation Reactions by Transition Metal-Free C(sp²)-H Functionalization