Citation: Wang Jintao, Xiong Jiukai, Li Juanjuan, Wang Jiali, Wang Kerang, Li Xiaoliu. Hydrogenation of Alkynes to cis-Alkenes with Hydrazine in Air[J]. Chinese Journal of Organic Chemistry, ;2017, 37(6): 1407-1411. doi: 10.6023/cjoc201701040 shu

Hydrogenation of Alkynes to cis-Alkenes with Hydrazine in Air

Key Laboratory of Medicinal Chemistry and Molecular Diagnosis of Ministry of Education, Key Laboratory of ChemicalBiology of Hebei Province, College of Chemistry and Environmental Science, Hebei University, Baoding 071002

Corresponding author: Wang Kerang, kerangwang@hbu.edu.cn Li Xiaoliu, lixl@hbu.edu.cn
Received Date: 20 January 2017
Revised Date: 19 February 2017

Fund Project: the Natural Science Foundation of Hebei Province 2016201031the National Natural Science Foundation of China 21372059the National Natural Science Foundation of China 21572044the Natural Science Foundation of Hebei Province B2016201254

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Transfer hydrogenation is a mild and effective way in reduction reaction. In this paper, a simple approach of selectively hydrogenation of alkynes to cis-alkenes with NH₂NH₂·H₂O as a transfer hydrogenation agent in the presence of air without any catalysts or metals was developed. Furthermore, the configuration of cis-alkene was confirmed by the 2D NOESY spectrum.
- transfer hydrogenation,
- hydrazine,
- alkynes,
- alkenes,
- diazene
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