Citation: Zheng Dongqing, Ma Haiyan, Ding Kai. A Practical Synthesis of Trifluoromethanesulfonate Esters[J]. Chinese Journal of Organic Chemistry, ;2017, 37(6): 1582-1584. doi: 10.6023/cjoc201701035 shu

A Practical Synthesis of Trifluoromethanesulfonate Esters

Zheng Dongqing ^a,b ,
Ma Haiyan ^b,*,, ,
Ding Kai ^a,*,,

a.
CAS Key Laboratory of Synthetic Chemistry of Natural Substances, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032
b.
Department of Chemistry, East China University of Science and Technology, Shanghai 200237

Corresponding author: Ma Haiyan, haiyanma@ecust.edu.cn Ding Kai, dingkai@mail.sioc.ac.cn
Received Date: 18 January 2017
Revised Date: 20 January 2017

Fund Project: the National Natural Science Foundation of China 20902098

Figures(3)

A practical synthesis of trifluoromethanesulfonate esters by reaction of orthoformate esters with triflic anhydride is described. The solvent-free method featured mild condition, short time, high yield, simple operation and broad substrate scope. The in situ generated trifluoromethanesulfonate ester is highly reactive alkylating agent, providing triflate ionic liquid in excellent yield via a one-pot procedure.
- trifluoromethanesulfonate ester,
- orthoester,
- triflic anhydride,
- one-pot alkylation
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