Citation: Li Chuntao, Wang Mengmeng, Zhu Qian, Cao Qianyong. A New Methoxy Poly(ethylene glycol)-anchored Anthracene for Fluorescence Sensing of Hg²⁺and Subsequent of Cysteine in Pure Aqueous Solution[J]. Chinese Journal of Organic Chemistry, ;2017, 37(6): 1443-1449. doi: 10.6023/cjoc201612056 shu

A New Methoxy Poly(ethylene glycol)-anchored Anthracene for Fluorescence Sensing of Hg²⁺and Subsequent of Cysteine in Pure Aqueous Solution

Key Laboratory of Poyang Lake Environment and Resource Utilization, Ministry of Education, Department of Chemistry, Nanchang University, Nanchang 330031

Corresponding author: Cao Qianyong, cqyong@ncu.edu.cn
Received Date: 23 December 2016
Revised Date: 25 January 2017

Fund Project: the National Natural Science Foundation of China 21462027

Figures(9)

A new Methoxy poly(ethylene glycol)-anchored polymer sensor P1, which contains anthracene fluorephore and di-2-picolylamine metal ions binding site, has been easily synthesized by "click reaction". In pure aqueous solution, P1 can coordinate with Hg²⁺ quickly to form 1:1 stoichiometry P1-Hg²⁺ complex, with quenching the fluorescence of P1. In addition, P1-Hg²⁺ shows exclusive fluorescence turn-on sensing of cysteine (Cys) over other amino acids for the displacement method.
- PEG,
- fluorescence,
- Cys recognition,
- anthracene,
- Hg²⁺
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

A New Methoxy Poly(ethylene glycol)-anchored Anthracene for Fluorescence Sensing of Hg2+and Subsequent of Cysteine in Pure Aqueous Solution

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通讯作者: 陈斌, bchen63@163.com

A New Methoxy Poly(ethylene glycol)-anchored Anthracene for Fluorescence Sensing of Hg²⁺and Subsequent of Cysteine in Pure Aqueous Solution