Citation: Jia Kanyan, Jiang Zhijiang, Yu Jingbo, Hong Zikun, Su Weike. An Efficient Synthesis of 2-Vinyl Furans/Thiophenes: Oxidative Heck Coupling under High-Speed Ball-Milling Conditions[J]. Chinese Journal of Organic Chemistry, ;2017, 37(6): 1473-1478. doi: 10.6023/cjoc201612047 shu

An Efficient Synthesis of 2-Vinyl Furans/Thiophenes: Oxidative Heck Coupling under High-Speed Ball-Milling Conditions

Jia Kanyan ^a ,
Jiang Zhijiang ^b ,
Yu Jingbo ^b ,
Hong Zikun ^a ,
Su Weike ^a,b,*,,

a.
College of Pharmaceutical Sciences, Zhejiang University of Technology, Hangzhou 310014
b.
Collaborative Innovation Center of Yangtze River Delta Region Green Pharmaceuticals, Zhejiang University of Technology, Hangzhou 310014

Corresponding author: Su Weike, pharmlab@zjut.edu.cn
Received Date: 18 December 2016
Revised Date: 8 February 2017

Fund Project: the Special Program for Key Basic Research of the Ministry of Science and Technology of China 2014CB460608the National Natural Science Foundation of China 21406201the National Natural Science Foundation of China 21276237

Figures(1)

An efficient synthesis of 2-vinyl furans and thiophenes through oxidative Heck reaction has been explored under solvent-less high-speed ball-milling conditions. This Pd-catalyzed oxidative Heck reaction proceeded well with both acrylates and styrenes, which afford desired product in 45 min, with moderate to high yields.
- high-speed ball-milling,
- oxidative Heck coupling,
- furan,
- thiophene
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