Citation: Lin Chunhua, Yuan Jianjun, Liu Deyong, Zhang Houfu, Xu Zhaohui. Efficient Synthesis of 5, 5-(Phenylmethylene)bis(2, 2-dimethyl-1, 3-dioxane-4, 6-dione) Derivatives in Biobased Gluconic Acid Aqueous Solution[J]. Chinese Journal of Organic Chemistry, ;2017, 37(6): 1560-1564. doi: 10.6023/cjoc201612044 shu

Efficient Synthesis of 5, 5-(Phenylmethylene)bis(2, 2-dimethyl-1, 3-dioxane-4, 6-dione) Derivatives in Biobased Gluconic Acid Aqueous Solution

a.
Chemistry and Chemical Engineering Department, Jiangxi Normal University, Nanchang 330022
b.
Jiangxi Traditional Chinese Medecine Institute, Nanchang 330026

Corresponding author: Xu Zhaohui, gotoxzh@163.com
Received Date: 14 December 2016
Revised Date: 24 January 2017

Fund Project: the Graduate Innovation Foundation of Jiangxi Province YC2015-B023the National Science and Technology Project 2001BA323C

Figures(2)

Six kinds of 5, 5-(phenylmethylene)bis(2, 2-dimethyl-1, 3-dioxane-4, 6-dione) derivatives were synthesized by the reaction of aromatic aldehydes and 2, 2-dimethyl-1, 3-dioxane-4, 6-dione in biobased gluconic acid aqueous solution at 40 ℃. The reaction has the advantages of high yields (81%~92%), mild conditions, simple operation and environmental friendliness. Furthermore, GAAS can be reused for several times.
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沈阳化工大学材料科学与工程学院沈阳 110142