Citation: Hou Shuhua, Wang Siqi, Qu Zhongguo, Zhong Keli, Bian Yanjiang, Tang Lijun. A Fluorescence Enhancement Probe for Trivalent Ions: Preparation and Property[J]. Chinese Journal of Organic Chemistry, ;2017, 37(3): 726-730. doi: 10.6023/cjoc201612004 shu

A Fluorescence Enhancement Probe for Trivalent Ions: Preparation and Property

Department of Chemistry, Bohai University, Jinzhou 121013

Corresponding author: Tang Lijun, bhutang@126.com
Received Date: 2 December 2016
Revised Date: 24 January 2017

Fund Project: the Program for Liaoning Excellent Talents in University LR2015001

Figures(7)

A novel rhodamine-based probe L was synthesized and characterized. The results showed that probe L acted as a fluorescent enhancement probe for Cr³⁺, Fe³⁺ and Al³⁺ recognition in CH₃OH/H₂O (V:V=8:2, c(Tris)=10 mmol/L, pH=7.2). L is highly selective to trivalent ions Cr³⁺, Fe³⁺ and Al³⁺ over other monovalent or divalent ions. Detection limits of probe L for Cr³⁺, Fe³⁺ and Al³⁺ are 2.1×10^-4, 2.3×10^-4 and 4.4×10^-4 mol/L, respectively, which make it have potentially application value in Cr³⁺, Fe³⁺ and Al³⁺ detection in various water samples.
- rhodamine,
- trivalent ions,
- fluorescence enhancement
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