Citation: Ma Xiaoli, Deng Ziyan, Yao Miaomiao, Zhong Mingdong, Li Wenling, Yang Zhi. Synthesis and Characterization of Two β-Diketiminato Tin(Ⅳ) Compounds[J]. Chinese Journal of Organic Chemistry, ;2017, 37(5): 1300-1305. doi: 10.6023/cjoc201611035 shu

Synthesis and Characterization of Two β-Diketiminato Tin(Ⅳ) Compounds

School of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing 100081

Corresponding author: Ma Xiaoli, maxiaoli@bit.edu.cn Yang Zhi, zhiyang@bit.edu.cn
Received Date: 25 November 2016
Revised Date: 30 December 2016

Fund Project: Project supported by the National Nature Science Foundation of China 21671018

Figures(4)

The reactions of L¹Li [L¹=HC(CMeNAr)₂, Ar=2, 6-ⁱPr₂C₆H₃] with Me₂SnCl₂, and L²Li [L²=HC(CMeNAr')₂, Ar'=2, 6-Et₂C₆H₃] with Me₃SnCl in a molar ratio of 1:1 were carried out at room temperature and acquired two new compounds, N(Ar)=C(Me)CH=C(NHAr)CH₂SnMe₂Cl·C₇H₈ (1) and [N(Ar')C(Me)=CHC(=NAr')CH₂SnMe₂]₂·CH₂Cl₂ (2), respectively. Different from regular nitrogen-metal-nitrogen bonds generated by the reactions of β-diketiminato ligands with metal halides, uncommon nitrogen-tin-carbon bonds in compounds 1 and 2 were obtained by Sn-N bond cleavage and concomitant Sn-C bond formation due to the Lewis acidity of SnMe₃ and SnMe₂Cl group. Compound 2 is a rare tin dimer with two resonant structures. Two compounds have been confirmed by ¹H NMR, ¹³C NMR, elemental analysis, and single crystal X-ray structural analysis. Through the comparison of compounds 1 and 2, the formation mechanism of dimer 2 has been investigated.
- β-diketiminato ligands,
- metal halides,
- tin dimer,
- nitrogen-tin-carbon bonds
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