Citation: Zhang Xun, Yang Nianfa. Poly[(S)-3-acrylamide-2, 2'-dihydroxy-1, 1'-binaphthyl]: Synthesis and Application in the Asymmetric Addition of Diethylzinc to Aromatic Aldehydes[J]. Chinese Journal of Organic Chemistry, ;2017, 37(4): 1027-1032. doi: 10.6023/cjoc201611027 shu

Poly[(S)-3-acrylamide-2, 2'-dihydroxy-1, 1'-binaphthyl]: Synthesis and Application in the Asymmetric Addition of Diethylzinc to Aromatic Aldehydes

Zhang Xun ,
Yang Nianfa ^*,,

Key Laboratory of Environmentally Friendly Chemistry and Applications of Ministry of Education, College of Chemistry, Xiangtan University, Xiangtan 411105

Corresponding author: Yang Nianfa, nianfayang@xtu.edu.cn
Received Date: 22 November 2016
Revised Date: 15 December 2016

Figures(4)

Poly[(S)-3-acrylamide-2, 2'-dihydroxy-1, 1'-binaphthyl] (poly-6) was synthesized through radical polymerization and applied in the asymmetric addition of diethylzinc to aromatic aldehydes, giving the optically active products up to 95% enantiomeric excess (ee). Besides, The poly-6 could be recycled up to six times without erosion of the enantioselectivity.
- polyacrylamide,
- 1, 1'-bi-2-naphthol,
- Et₂Zn,
- aromatic aldehydes,
- asymmetric addition
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