Citation: Huang Ling, Zhu Zheng, Cao Tianhua, Lei Xueying, Gong Jiuhan, Guo Shengmei, Cai Hu. Rapid, Practical and Efficient Synthesis of Enol Phosphates from β-Keto Esters and Phosphites[J]. Chinese Journal of Organic Chemistry, ;2017, 37(6): 1571-1576. doi: 10.6023/cjoc201611018 shu

Rapid, Practical and Efficient Synthesis of Enol Phosphates from β-Keto Esters and Phosphites

College of Chemistry, Nanchang University, Nanchang 330031

Corresponding author: Guo Shengmei, Cai Hu, caihu@ncu.edu.cn
Received Date: 16 November 2016
Revised Date: 12 January 2017

Fund Project: the National Natural Science Foundation of China 21302084the National Key Basic Research Program of China 973 Programthe National Key Basic Research Program of China 2012CBA01204

Figures(1)

A useful strategy for the synthesis of enol phosphates from β-keto esters via Atherton-Atodd reaction was developed. A variety of enol phosphates can be quickly and readily prepared with broad substrate scope and moderate yields under mild conditions. This method provides a low cost and practical way to synthesize enol phosphates from β-keto esters.
- enol phosphate,
- β-keto ester,
- Atherton-Todd reaction
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