Citation: Li Yingjun, Li Jiyang, Xu Yongting, Jin Kun, Cao Xin. Highly Selective Naked-Eye and Fluorescence Probe for Cu²⁺ Based on Carbazole Schiff-Base[J]. Chinese Journal of Organic Chemistry, ;2017, 37(4): 896-901. doi: 10.6023/cjoc201611014 shu

Highly Selective Naked-Eye and Fluorescence Probe for Cu²⁺ Based on Carbazole Schiff-Base

Li Yingjun ^a,*,, ,
Li Jiyang ^a ,
Xu Yongting ^a ,
Jin Kun ^b ,
Cao Xin ^a

a.
College of Chemistry and Chemical Engineering, Liaoning Normal University, Dalian 116029
b.
State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116012

Corresponding author: Li Yingjun, chemlab.lnnu@163.com
Received Date: 12 November 2016
Revised Date: 26 December 2016

Fund Project: the Natural Science Foundation of Liaoning Province 20102126

Figures(9)

A new fluorescence probe L based on carbazole Schiff-base for Cu²⁺ was synthesized. The recognition ability of probe L to metal ions was investigated by UV-Vis and fluorescence spectra. The experimental results showed that the probe L in CH₃CN displayed a distinct color change from yellow to colorless upon the addition of Cu²⁺, which can be directly detected by the naked eye for Cu²⁺. The fluorescence spectra showed that the probe L had high selective and sensitive recognition toward Cu²⁺ in CH₃CN, the fluorescence intensity was increased with the increase of Cu²⁺ concentration, and it was not affected by other metal ions. The association constant between the probe L and Cu²⁺ was detected to be 1.38×10⁴ L/mol and the corresponding detection limit was calculated to be 2.34×10^-7 mol/L. The detection limit of L for Cu²⁺ was far lower than the maximum allowable level of the WHO limit (20 mmol/L) for drinking water. The results indicate that the probe L should be applicable to the research on the environmental applications associated with Cu²⁺.
- carbazole,
- Schiff base,
- naked-eye recognition,
- Cu²⁺ fluorescence probe
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Highly Selective Naked-Eye and Fluorescence Probe for Cu2+ Based on Carbazole Schiff-Base

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Highly Selective Naked-Eye and Fluorescence Probe for Cu²⁺ Based on Carbazole Schiff-Base