Citation: Yan Xiaohui, Li Jiarong, Zhang Qi, Shi Daxin. Synthesis of Nitroarenes under Microwave[J]. Chinese Journal of Organic Chemistry, ;2017, 37(6): 1450-1455. doi: 10.6023/cjoc201610030 shu

Synthesis of Nitroarenes under Microwave

School of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing 102488

Corresponding author: Shi Daxin, shidaxin@bit.edu.cn
Received Date: 18 October 2016
Revised Date: 18 January 2017

The reaction of arylboronic acids with bismuth(Ⅲ) nitrate pentahydrate resulted in a series of nitroarenes when the reaction was carried out under microwave (120 ℃) for 1 min in 1, 2-dichloroethane. Compared with traditional heating condition, the method of microwave condition for the preparation of nitroarenes was simple, efficient, time-saving, and of less by-products. In addition, possible free radical mechanism was proposed.
- arylboronic acids,
- bismuth(Ⅲ) nitrate pentahydrate,
- nitroarenes,
- microwave,
- free radical conversion
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