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Citation: Tong Qing, Gao Qiang, Xu Bolian, Yu Lei, Fan Yining. Pt/WO3/ZrO2-Catalyzed Selective Hydrogenolysis of Glycerol to Produce 1, 3-Propanediol[J]. Chinese Journal of Organic Chemistry, ;2017, 37(3): 753-758. doi: 10.6023/cjoc201610002 shu

Pt/WO3/ZrO2-Catalyzed Selective Hydrogenolysis of Glycerol to Produce 1, 3-Propanediol

  • a.

    Key Laboratory of Mesoscopic Chemistry of Ministry of Education, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093

  • b.

    Nanjing University-Yangzhou Chemistry and Chemical Engineering Institute, Yangzhou 211400

  • c.

    School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou 225002

  • Corresponding author: Yu Lei, yulei@yzu.edu.cn Fan Yining, ynfan@nju.edu.cn
  • Received Date: 1 October 2016
    Revised Date: 16 November 2016

    Fund Project: the National Natural Science Fundation of China 21202141the Priority Academic Program Development of Jiangsu Higher Education Institutions, and the Key Science & Technology Specific Projects of Yangzhou YZ20122029

Figures(2)

  • Glycerol is an abundantly generated biomass and conversion of this compound into useful chemicals is of significant industrial value. Hydrogenolysis of glycerol produces a series of C-3 alcohols, such as 1-propanol, 2-propanol, 1, 2-pro-panediol and 1, 3-propanediol (1, 3-PDO). Among these compounds, 1, 3-PDO is an important organic intermediate to synthesize poly-trimethylene-terephthalate. Therefore, synthesis of 1, 3-PDO through the selective hydrogenolysis of glycerol is a promising subject. Recently, during our investigations on the Pt/WO3/ZrO2-catalyzed glycerol hydrolysis, it was found that the acidity of the catalyst could be controlled by tungsten oxide content and the glycerol conversion was largely improved with high 1, 3-PDO selectivity. The technology largely improved the synthetic efficiency and is of potential industrial application value.
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