Citation: Zhao Fei, Jia Xiuwen, Wang Dongping, Fei Chaoli, Wu Chenglin, Wang Jiang, Liu Hong. Research Progress in Metal-Catalyzed Addition of Carbon-Hetero Bonds to Alkynes[J]. Chinese Journal of Organic Chemistry, ;2017, 37(2): 284-300. doi: 10.6023/cjoc201607035 shu

Research Progress in Metal-Catalyzed Addition of Carbon-Hetero Bonds to Alkynes

Zhao Fei ^a ,
Jia Xiuwen ^a ,
Wang Dongping ^a ,
Fei Chaoli ^a ,
Wu Chenglin ^b,c ,
Wang Jiang ^b,c ,
Liu Hong ^b,c,*,,

a.
Antibiotics Research and Re-evaluation Key Laboratory of Sichuan Province, Sichuan Industrial Institute of Antibiotics, Chengdu University, Chengdu 610052
b.
Key Laboratory of Receptor Research, Shanghai Institute of Materia Medica, Chinese Academy of Sciences, Shanghai 201203
c.
University of Chinese Academy of Sciences, Beijing 100049

Corresponding author: Liu Hong, hliu@mail.shcnc.ac.cn
Received Date: 21 July 2016
Revised Date: 14 October 2016

Fund Project: the National Natural Science Foundation of China 21372235the National Natural Science Foundation of China 21602022Re-evaluation Key Laboratory of Sichuan Province ARRLKF15-01

Figures(35)

The addition of carbon-hetero bonds to alkynes has become an important apporach for the functionalization of carbon-carbon triple bonds. It can construct two bonds, namely one carbon-carbon bond and one carbon-hetero bond, in a single one step. These addition reactions feature high efficiency and high atom-economy. In recent years, metal-catalyzed (Al, Fe, Ni, Cu, Ga, Ru, Rh, Pd, Hf, Ir, Pt, Au, Bi, etc.) addition of many various kinds of carbon-hetero bonds to alkynes has achieved lots of important developments. According to the types of carbon-hetero bonds, the addition of 8 different kinds of carbon-hetero bonds [C-H, C-B, C-N, C-O, C-Si, C-S, C-X (X=Cl, Br, I), C-Se] to alkynes is reviewed in this paper, and the reaction conditions, reaction selectivities (regioselectivities and stereoselectivities) and reaction mechanisms are also discussed and summarized.
- metal-catalyzed,
- carbon-hetero bonds,
- alkynes,
- addition reactions
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沈阳化工大学材料科学与工程学院沈阳 110142