Citation: Zhou Chan, Qiu Bo, Zeng Yi, Chen Jinping, Yu Tianjun, Li Yi. A Reaction-Based Chemsensor for Hydrogen Sulfide Detection with Fluorescence Enhancement[J]. Chinese Journal of Organic Chemistry, ;2017, 37(1): 92-96. doi: 10.6023/cjoc201607034 shu

A Reaction-Based Chemsensor for Hydrogen Sulfide Detection with Fluorescence Enhancement

Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190

Corresponding author: Zeng Yi, zengyi@mail.ipc.ac.cn Li Yi, yili@mail.ipc.ac.cn
Received Date: 20 July 2016
Revised Date: 8 October 2016

Fund Project: the the National Natural Science Foundation of China 21233011the State Key Development Program for Basic Research of China 2013CB834505the State Key Development Program for Basic Research of China 973 Programthe State Key Development Program for Basic Research of China 2013CB834703

Figures(4)

A reaction-based probe 8-(2, 4-dinitrophenoxy) pyrene-1-carbaldehyde (PCNP) for H₂S detection was designed and synthesized by utilizing 8-hydroxypyrene-1-carbaldehyde and dinitrophenyl ether as the reporting chromophore and the recognition unit, respectively.The probe was dissolved in phosphate buffer saline (PBS) with cetyltrimethyl ammonium bromide (CTAB), and the sensing ability toward H₂S was investigated with steady-state spectroscopy.The emission of PCNP was quenched by photoinduced electron transfer without H₂S.The fluorescence of PCNP was boosted after thiolysis reaction in the presence of H₂S, showing orange red emission.The fluorescence response was rapid and reached a maximum enhancement of about 260 times in the presence of 0.1 mmol·L^-1 H₂S, giving a reaction rate constant of 0.20 min^-1.The limit of detection of PCNP is estimated to be 0.10 μmol·L^-1.The results demonstrate that PCNP is capable of detecting H₂S rapidly, sensitively and selectively.
- fluorescent sensor,
- reaction-based sensor,
- thiolysis reaction,
- fluorescence enhancement,
- hydrogen sulfide
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