Citation: Li Wei, Yang Chao, Gao Guolin, Xia Wujiong. Na₂S₂O₈ Promoted Direct Thiocyanates from Thiols: a Practical Method for the Synthesis of Thiocyanates[J]. Chinese Journal of Organic Chemistry, ;2017, 37(2): 480-484. doi: 10.6023/cjoc201607019 shu

Na₂S₂O₈ Promoted Direct Thiocyanates from Thiols: a Practical Method for the Synthesis of Thiocyanates

Li Wei ^a,b ,
Yang Chao ^a,*,, ,
Gao Guolin ^a ,
Xia Wujiong ^a,*,,

a.
State Key Laboratory of Urban Water Resource and Environment, Shenzhen Graduate School, Harbin Institute of Technology, Harbin 150080
b.
Key Laboratory for Food Science and Engineering, Harbin University of Commerce, Harbin 150076

Corresponding author: Yang Chao, xyyang@hit.edu.cn Xia Wujiong, xiawj@hit.edu.cn
Received Date: 12 July 2016
Revised Date: 2 September 2016

Figures(2)

A metal-free method for the preparation of thiocyanates through Na₂S₂O₈/DBU (1, 8-diazabicyclo[5.4.0]undec-7-ene)-promoted direct thiocyanation of thiols with NaCN was developed. The reaction was run under mild conditions, and the products were obtained in 31%~78% yields.
- thiocyanates,
- sodium persulfate,
- metal-free,
- thiol
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Na2S2O8 Promoted Direct Thiocyanates from Thiols: a Practical Method for the Synthesis of Thiocyanates

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Na₂S₂O₈ Promoted Direct Thiocyanates from Thiols: a Practical Method for the Synthesis of Thiocyanates