Citation: Zhu Jianghua, Fan Xiangtian, Jiang Ping, Cao Qianyong. A Tripodal Anthracene-Appended Triazole for Fluorescence Sensing of Hg²⁺[J]. Chinese Journal of Organic Chemistry, ;2017, 37(1): 185-189. doi: 10.6023/cjoc201606036 shu

A Tripodal Anthracene-Appended Triazole for Fluorescence Sensing of Hg²⁺

Department of Chemistry, Nanchang University, Nanchang 330031

Corresponding author: Cao Qianyong, cqyong@ncu.edu.cn
Received Date: 23 June 2016
Revised Date: 25 July 2016

Fund Project: the National Natural Science Foundation of China 21162017the National Natural Science Foundation of China 21462027

Figures(6)

A new anthracene-containing tripodal triazole with 1, 3, 5-trisubstituted benzene core has been easily synthesized by "click reaction".Among various metal ions, 1 shows exclusive fluorescence turn-off sensing of Hg²⁺ in CH₃CN-H₂O (V:V=9:1) solution.The quenching ration is about 75%, and the detection limit for Hg²⁺ is 6.1×10^-6 mol/L.The ¹H NMR titrations results reveal that the N atoms of the three triazoles of 1 take part in binding with center ion with forming 1:1 1-Zn²⁺ complex.
- tripodal receptor,
- triazole,
- anthracene,
- mercury ion,
- fluorescence sensing
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沈阳化工大学材料科学与工程学院沈阳 110142

A Tripodal Anthracene-Appended Triazole for Fluorescence Sensing of Hg2+

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通讯作者: 陈斌, bchen63@163.com

A Tripodal Anthracene-Appended Triazole for Fluorescence Sensing of Hg²⁺