Citation: Sun Wangbin, Sun Bingfeng, Zou Jianping. Manganese (Ⅲ)-Mediated Alkenyl C (sp²)-P Bond Formation from the Reaction of α, β-Unsaturated Sulfones with Dialkyl Phosphites[J]. Chinese Journal of Organic Chemistry, ;2017, 37(1): 79-85. doi: 10.6023/cjoc201606031 shu

Manganese (Ⅲ)-Mediated Alkenyl C (sp²)-P Bond Formation from the Reaction of α, β-Unsaturated Sulfones with Dialkyl Phosphites

Sun Wangbin ^a,b ,
Sun Bingfeng ^b,*,, ,
Zou Jianping ^a,b,*,,

a.
College of Chemistry and Chemical Engineering, Soochow University, Suzhou 215123
b.
Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032

Corresponding author: Sun Bingfeng, bfsun@sioc.ac.cn Zou Jianping, jpzou@suda.edu.cn
Received Date: 21 June 2016
Revised Date: 26 August 2016

Fund Project: the National Natural Science Foundation of China 21472133the National Natural Science Foundation of China 21172163the National Natural Science Foundation of China 20772088

Figures(3)

Mn (OAc)₃-mediated reaction of dialkyl phosphites with α, β-unsaturated sulfones to form α, β-unsaturated phosphonates is described.This reaction proceeded in acetic acid at 80℃ for 2 h to afford selective (E)-2-alkenyl phosphonates in 40%~72% yields.
- Mn (OAc)₃,
- phosphonyl radical,
- α, β-unsaturated sulfone,
- alkenyl phosphonate
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Manganese (Ⅲ)-Mediated Alkenyl C (sp2)-P Bond Formation from the Reaction of α, β-Unsaturated Sulfones with Dialkyl Phosphites

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Manganese (Ⅲ)-Mediated Alkenyl C (sp²)-P Bond Formation from the Reaction of α, β-Unsaturated Sulfones with Dialkyl Phosphites