Citation: Gao Anli, Ye Qingsong, Yu Juan, Liu Weiping. Research Advances of the Chiral Binap-Ru (Ⅱ) Catalysts in Asymmetric Hydrogenation Reactions[J]. Chinese Journal of Organic Chemistry, ;2017, 37(1): 47-78. doi: 10.6023/cjoc201606024 shu

Research Advances of the Chiral Binap-Ru (Ⅱ) Catalysts in Asymmetric Hydrogenation Reactions

State Key Laboratory of Advanced Technologies for Comprehensive Utilization of Platinum Metals, Kunming Institute of Precious Metals, Kunming 650106

Corresponding author: Liu Weiping, liuweiping0917@126.com
Received Date: 14 June 2016
Revised Date: 12 August 2016

Fund Project: the Yunnan Province Scientific Creative Plan 2015AA006the 12th National Scientific Support Plan 2012BAE06B08the Yunnan Province Scientific Creative Plan 2013B019

Figures(26)

Chiral 2, 2'-bis (diphenylphosphino)-1, 1'-binapthyl (Binap) ligand consists of a pair of 2-diphenylphosphinonaphthyl groups connected at the 1 and 1'positions, being of the nature of the C₂-axial chirality with optical activity of ±234°.The Binap can coordinate with many transitional metals to form stable chelation complexes, effecting the chirality transfer to the metal center for function in asymmetrically catalytic reactions.This contribution is focused on the Binap-Ru (Ⅱ) catalytic system that covers the various substrates, reaction conditions, enantioselectivity of the products, reaction mechanism, and others on the basis of the prepared stable Binap-Ru (Ⅱ) complexes as the clue in the text.This study will give a deep understanding of this system especially concerning the applied catalytic synthesis of the useful organic molecules.
- Binap ligand,
- chiral ruthenium complexes,
- asymmetric catalysis,
- reaction mechanism,
- application
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