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Citation: Huang Feng, Xu Pengxiang, Lü Yisheng, Lin Shaoliang. Polymerization-Induced Self-Assembly of ABC Triblock Copolymer[J]. Chinese Journal of Organic Chemistry, ;2016, 36(9): 2220-2224. doi: 10.6023/cjoc201605023 shu

Polymerization-Induced Self-Assembly of ABC Triblock Copolymer

1.
School of Materials Science and Engineering, East China University of Science and Technology, Shanghai 200237

Corresponding author: Lin Shaoliang, slin@escust.edu.cn
Received Date: 14 May 2016
Revised Date: 22 May 2016

Fund Project: the Fundamental Research Funds for the Central Universities B14018and the Project of Shanghai Municipality 14SG29the Fundamental Research Funds for the Central Universities WD1213002Project supported by the National Natural Science Foundation of China 51573046Project supported by the National Natural Science Foundation of China 51622301

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Polymerization-induced self-assembly (PISA) is a new robust strategy to produce concentrated dispersions of block copolymer nano-objects. Insight into the dynamic process can promote the development of PISA by computer simulations. In this work, dissipative particle dynamics simulations (DPD) with a reaction model were employed to investigate the PISA behavior of ABC triblock copolymer. The polymerization of solvophobic B block was firstly performed using solvophilic macromolecular initiator A to fabricate AB copolymer. The continuous morphology transition from spherical micelle to wormlike micelle, to lamellae and finally to vesicle was observed during the process. Then, the polymerization of C block was further carried out and induced the different ABC triblock copolymer aggregates by tuning the interaction between C block and solvent (solvophobic or solvophilic).
- polymerization,
- self-assembly,
- dissipative particle dynamics,
- simulation
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