Citation: Xu Huiting, Zhang Chaohuai, Chen Gang, Shen Runpu, Ying Anguo. Application of Task-Specific Ionic liquids to Organic Synthesis[J]. Chinese Journal of Organic Chemistry, ;2016, 36(10): 2353-2367. doi: 10.6023/cjoc201604053 shu

Application of Task-Specific Ionic liquids to Organic Synthesis

Xu Huiting ^a ,
Zhang Chaohuai ^b ,
Chen Gang ^b ,
Shen Runpu ^a,*,, ,
Ying Anguo ^b,*,,

a.
School of Chemistry and Chemical Engineering, Shaoxing University, Shaoxing 312000
b.
School of Pharmaceutical and Chemical Engineering, Taizhou University, Taizhou 318000

Corresponding author: Shen Runpu, srunpu@usx.edu.cn Ying Anguo, yinganguo@163.com
Received Date: 26 April 2016
Revised Date: 28 May 2016

Fund Project: the National Natural Science Foundation of China Nos.21576176，21106090and the Science and Technology Innovation Undergraduate Program of Zhejiang Province No.2015R430015Project supported by the Natural Science Foundation of Zhejiang Province No.LY15B060002

Figures(12)

Ionic liquids (ILs) have been widely used as green reaction solvents and/or catalysts in organic synthesis due to their advantages, including low volatility, good thermal stability, good solubility and recyclability. ILs have played a significant role in accelerating reaction rate and selectivity. The recent advances in the application of ILs as catalysts or solvents are summarized in this review, such as in Baylis-Hillman reaction, Michael addition, oxidation and reduction reaction, Knoevenagel condensation, aldol reaction, Diels-Alder reaction, Heck coupling reaction, Suzuki reaction, asymmetric reaction, Biginelli reaction, Mannich reaction and Hantzsch reaction. Relationship between structure and catalytic efficiency of ILs as well as plausible mechanism has been discussed, which is beneficial to develop the novel task-specific ionic liquids with diverse functionalities.
- task-specific ionic liquids,
- organic synthesis,
- relationship between structure and activity,
- green chemistry,
- recy-clability
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