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Citation: Xiao Shiji, Xu Delin, Fu Shaobin, Zhang Maosheng, Ding Lisheng, Zhou Yan. Two New Nitrogen Compounds from Gymnotheca involucrata[J]. Chinese Journal of Organic Chemistry, ;2016, 36(10): 2496-2498. doi: 10.6023/cjoc201604012 shu

Two New Nitrogen Compounds from Gymnotheca involucrata

Xiao Shiji ^a,*,, ,
Xu Delin ^a ,
Fu Shaobin ^a ,
Zhang Maosheng ^a ,
Ding Lisheng ^b ,
Zhou Yan ^b

a.
School of Pharmacy, Zunyi Medical University, Zunyi 563003
b.
Chengdu Institute of Biology, Chinese Academy of Sciences, Chengdu 610041

Corresponding author: Xiao Shiji, sjxiao@zmc.edu.cn
Received Date: 6 April 2016
Revised Date: 8 May 2016

Fund Project: Project supported by the National Natural Sciences Foundation of China No.31560102

Figures(2)

By silica gel, MCI column chromatographic and preparative HPLC (high performance liquid chromatography) technologies, six nitrogen compounds were isolated from the whole parts of Gymnotheca involucrata. By using spectroscopic techniques including NMR and MS, these compounds were identified as 2-(1-hydroxy-6-methoxy-4-oxocyclohexa-2-ene- 1-yl)acetonitrile (1), 10-methoxy-1-oxa-3-azaspiro[4.5]dec-2,6-diene-8-one (2), 2-(1-hydroxy-4-oxocyclohexa-2,5-dien-1-yl)- acetonitrile (3), 1-oxa-3-azaspiro[4.5]dec-2-ene-8-one (4), 1-oxa-3-azaspiro[4.5]dec-2,6-diene-8-one (5) and 4-hydroxybenzyl acetonitrile (6). Compounds 1 and 2 are new compounds, compound 3 is a new natural product, and compounds 4~6 were isolated from this plant for the first time.
- Gymnotheca involucrata,
- saururaceae,
- nitrogen compound,
- chemical constituent
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