Citation: Wu Ruihua, Yang Wen, Cheng Guo, Li Yue, Yang Dingqiao. Progress in Transition Metal-Catalyzed Asymmetric Ring-Opening Reactions of Oxa(Aza)bicyclic Alkenes with Carbanion Nucleophiles[J]. Chinese Journal of Organic Chemistry, ;2016, 36(10): 2368-2379. doi: 10.6023/cjoc201604006 shu

Progress in Transition Metal-Catalyzed Asymmetric Ring-Opening Reactions of Oxa(Aza)bicyclic Alkenes with Carbanion Nucleophiles

1.
Key Laboratory of Theoretical Chemistry of Environment, Ministry of Education, School of Chemistry and Environment, South China Normal University, Guangzhou 510006

Corresponding author: Yang Dingqiao, yangdq@scnu.edu.cn
Received Date: 3 April 2016
Revised Date: 17 May 2016

Fund Project: and the City of Guangzhou Science and Technology Plan Projects No.156300018the Natural Science Foundation of Guangdong Province No.S2013020013091Project supported by the National Natural Science Foundation of China Nos.21172081, 21372090

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The recent progress in transition metal-catalyzed asymmetric ring-opening reactions of oxa(aza)bicyclic alkenes with carbanion nucleophiles is reviewed with focus on the influence of the types of transition metal catalysts, carbanion nucleophiles, ligands, the structures of oxa(aza)bicyclic alkenes, solvents and additives on the asymmetric ring-opening reactions. Moreover, the parties of possible mechanisms for the asymmetric ring-opening reactions are also discussed.
- transition metal catalyst,
- oxa(aza)bicyclic alkene,
- carbanion nucleophile,
- asymmetric ring-opening
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