Citation: Xu Xing, Xu Dongcheng, Li Xinsheng. 1,2-Di-tert-butyldiaziridinone-Cu Catalyzed Oxidation of Alkenes to Ketones[J]. Chinese Journal of Organic Chemistry, ;2016, 36(10): 2479-2483. doi: 10.6023/cjoc201603028 shu

1,2-Di-tert-butyldiaziridinone-Cu Catalyzed Oxidation of Alkenes to Ketones

1.
College of Chemistry and Life Science, Zhejiang Normal University, Jinhua 321004

Corresponding author: Li Xinsheng, ssky33@zjnu.cn
Received Date: 16 March 2016
Revised Date: 30 May 2016

Fund Project:

Oxidation of 1,1-disubstituted alkenes to ketones in the complex of CuBr and 1,2-di-tert-butyldiaziridinone in CH₂Cl₂ was researched. The reaction offered high yields (up to 91%) with low catalyst loading and mild conditions. The method provided a good choice for the oxidative cleavage of terminal olefins to ketones.
- CuBr,
- 1,2-di-tert-butyldiaziridinone,
- alkene,
- oxidation
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沈阳化工大学材料科学与工程学院沈阳 110142