Citation: Tian Wenyan, Xu Song, Liang Zhongwei, Sun Deli, Zhang Ronghua. Synthesis of Oxindoles by Eosin Y Catalyzed under Visible Light[J]. Chinese Journal of Organic Chemistry, ;2016, 36(9): 2121-2129. doi: 10.6023/cjoc201603002 shu

Synthesis of Oxindoles by Eosin Y Catalyzed under Visible Light

Tian Wenyan ^1,2 ,
Xu Song ^1,2,3 ,
Liang Zhongwei ^1,2 ,
Sun Deli ^1,2 ,
Zhang Ronghua ^1,2,*,,

a.
Department of Chemistry, Tongji University, Shanghai 200092
b.
Shanghai Key Laboratory of Chemical Assessment and Sustainability, Shanghai 200092
c.
College of Biological, Chemical Sciences and Engineering, Jiaxing University, Jiaxing 31400

Corresponding author: Zhang Ronghua, rhzhang@tongji.edu.cn
Received Date: 3 March 2016
Revised Date: 29 April 2016

Fund Project: Project supported by the National Natural Science Foundation of China 20972113Project supported by the National Natural Science Foundation of China B020502

Figures(2)

A novel visible-light-introduced reaction for the construction of oxindole derivatives via tandem radical cyclization of N-aryl acrylamides with diethyl bromomalonate has been developed. The reaction has been achieved in high yield under mild conditions by using Eosin Y as photocatalyst, which is cheap, easy to handle and environmentally friendly. It might provide a promising protocol for the synthesis of oxindole derivatives.
- eosin Y,
- photoredox catalysis,
- oxindoles,
- radical cyclization
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