Citation: Song Chuang, Mao Guoliang, Liu Zhenhua, Ning Yingnan, Jiang Tao. Advances in Mechanistic Research of Ethylene Selective Oligomeri-zation Catalyzed by Homogeneous Chromium-Based Catalysts[J]. Chinese Journal of Organic Chemistry, ;2016, 36(9): 2105-2120. doi: 10.6023/cjoc201602034 shu

Advances in Mechanistic Research of Ethylene Selective Oligomeri-zation Catalyzed by Homogeneous Chromium-Based Catalysts

a.
Provincial Key Laboratory of Oil & Gas Chemical Technology, College of Chemistry and Chemical Engineering, Northeast Petroleum University, Daqing 163318
b.
College of Material Science and Chemical Engineering, Tianjin University of Science & Technology, Tianjin 300222

Corresponding author: Mao Guoliang, maoguoliang@nepu.edu.cn
Received Date: 29 February 2016
Revised Date: 21 April 2016

Fund Project: Project supported by the National Natural Science Foundation of China 51534004the Program for New Century Excellent Talents in University NCET-07-0142Project supported by the National Natural Science Foundation of China U1362110

Figures(22)

Linear α-olefin is an important feed stock for chemical industry. Production of specific α-olefin through selective ethylene oligomerization catalyzed by homogeneous chromium-based catalysts is an important research on orientation under rapid development in recent years. The research of catalytic mechanism plays an important role in guiding the exploration of novel high-efficient catalysts. The application of methods such as labelled atom, organometallic precursor, EPR-XAS, density functional theory (DFT) calculation etc. in the research of reaction path and the metal oxidation state is introduced, with the latest achievement in the mechanistic research summarized. Research works carried out by various researchers are compared and discussed from methodology. New perspective on binuclear Cr metal ring mechanistic research is proposed and an outlook on the further research orientation is presented.
- ethylene,
- chromium-based catalyst,
- metal complex,
- catalyst activation,
- selective oligomerization,
- mechanism research
1. [1]
  Skupinska, J.Chem.Rev.1991, 91, 613. doi: 10.1021/cr00004a007
2. [2]
  Forestière A.; Olivier-Bourbigou H.; Saussine L.Oil Gas Sci.Technol.2009, 64, 649. doi: 10.2516/ogst/2009027
3. [3]
  Qian, B.Z.Petrochem.Ind.Technol.2011, 18, 58(in Chinese).
4. [4]
  Jin, W.Petroleum.Knowl.2014, 4, 24(in Chinese).
5. [5]
  Carter, A.; Cohen, S.A.; Cooley, N.A.; Murphy, A.; Scutt, J.; Wass, D.F.Chem.Commun.2002, 8, 858.
6. [6]
  Commereuc, D.; Chauvin, Y.; Gaillard, J.; Leonard, J.; Andrews, J.Hydrocarbon Process.1984, 63, 118.
7. [7]
  Al-Jarallah, A.M.; Anabtawi, J.A.; Siddiqui, M.A.B.; Aitani, A.M.; Al-Sa'doun, A.W.Catal.Today 1992, 14, 1. doi: 10.1016/0920-5861(92)80128-A
8. [8]
  Pillai, S.M.; Ravindranathan, M.; Sivaram, S.Chem.Rev.1986, 86, 353. doi: 10.1021/cr00072a004
9. [9]
  Al-Sherehy, F.A.Stud.Surf.Sci.Catal.1996, 100, 515. doi: 10.1016/S0167-2991(96)80052-8
10. [10]
  Van Leeuwen, P.W.; Clément, N.D.; Tschan, M.J.L.Coord.Chem.Rev.2011, 255, 1499. doi: 10.1016/j.ccr.2010.10.009
11. [11]
  Xu, J.Y.Pet.Process.Petrochem.2014, 45, 67(in Chinese).
12. [12]
  McGuinness, D.S.Chem.Rev.2010, 111, 2321.
13. [13]
  Agapie, T.Coord.Chem.Rev.2011, 255, 861. doi: 10.1016/j.ccr.2010.11.035
14. [14]
  Bryliakov, K.P.; Talsi, E.P.Coord.Chem.Rev.2012, 256, 2994. doi: 10.1016/j.ccr.2012.06.023
15. [15]
  Dixon, J.T.; Green, M.J.; Hess, F.M.; Morgan, D.H.J.Organomet.Chem.2004, 689, 3641. doi: 10.1016/j.jorganchem.2004.06.008
16. [16]
  Belov, G.P.Pet.Chem.2012, 52, 139. doi: 10.1134/S0965544112030036
17. [17]
  Suttil, J.A.; McGuinness, D.S.Organometallics 2012, 31, 7004. doi: 10.1021/om3008508
18. [18]
  Ziegler, K.; Martin, H.US 2943125, 1960[Chem.Abstr.1983, 54, 134637].
19. [19]
  Belov, G.P.; Dzhabiev, T.S.; Kolesnikov, I.M.J.Mol.Catal.1982, 14, 105. doi: 10.1016/0304-5102(82)80053-9
20. [20]
  Robinson Jr, R.; McGuinness, D.S.; Yates, B.F.ACS Catal.2013, 3, 3006. doi: 10.1021/cs4006875
21. [21]
  Al-Sa'doun, A.W.Appl.Catal., A 1993, 105, 1. doi: 10.1016/0926-860X(93)85131-8
22. [22]
  McDermott, J.X.; White, J.F.; Whitesides, G.M.J.Am.Chem.Soc.1973, 95, 4451. doi: 10.1021/ja00794a068
23. [23]
  Manyik, R.M.; Walker, W.E.; Wilson, T.P.J.Catal.1977, 47, 197. doi: 10.1016/0021-9517(77)90167-1
24. [24]
  Pettijohn, T.M.; Reagen, W.K.; Martin, S.J.US 5331070, 1994[Chem.Abstr.1994, 122, 56808].
25. [25]
  Reagen, W.K.; Pettijohn, T.M.; Freeman, J.W.; Benham, E.A.US 5786431, 1998[Chem.Abstr.1998, 115, 93172].
26. [26]
  Freeman, J.W.; Buster, J.L.; Knudsen, R.D.US 5919996, 1999[Chem.Abstr.1999, 130, 95984].
27. [27]
  Briggs, J.R.J.Chem.Soc., Chem.Commun.1989, 11, 674.
28. [28]
  Emrich, R.; Heinemann, O.; Jolly, P.W., Krüger, C.; Verhovnik, G.P.Organometallics 1997, 16, 1511. doi: 10.1021/om961044c
29. [29]
  Liu, R.; Xiao, S.M.; Zhong, X.H.; Cao, Y.C.; Liang, S.B.; Liu, Z.Y.; Ye, X.F.; Shen, A.; Zhu, H.P.Chin.J.Org.Chem.2015, 35, 1861(in Chinese). doi: 10.6023/cjoc201504009
30. [30]
  Agapie, T.; Schofer, S.J.; Labinger, J.A.; Bercaw, J.E.J.Am.Chem.Soc.2004, 126, 1304. doi: 10.1021/ja038968t
31. [31]
  Agapie, T.; Labinger, J.A.; Bercaw, J.E.J.Am.Chem.Soc.2007, 129, 14281. doi: 10.1021/ja073493h
32. [32]
  Klemps, C.; Payet, E.; Magna, L.; Saussine, L.; Le Goff, X.F.; Le Floch, P.Chem.Eur.J.2009, 15, 8259. doi: 10.1002/chem.v15:33
33. [33]
  Yang, Y.; Liu, Z.; Zhong, L.; Qiu, P.Y.; Dong, Q.; Cheng, R.H.; Vanderbilt, J.; Liu, B.P.Organometallics 2011, 30, 5297. doi: 10.1021/om200722r
34. [34]
  Yu, Z.X.; Houk, K.N.Angew.Chem., Int.Ed.2003, 42, 808. doi: 10.1002/anie.200390215
35. [35]
  Qi, Y.; Dong, Q.; Zhong, L.; Liu, Z.; Qiu, P.; Cheng, R.H.; He, X.L.; Vanderbilt, J.; Liu, B.P.Organometallics 2010, 29, 1588. doi: 10.1021/om900917k
36. [36]
  Budzelaar, P.H.Can.J.Chem.2009, 87, 832.
37. [37]
  Albahily, K.; Koç, E.; Al-Baldawi, D.; Savard, D.; Gambarotta, S.; Burchell, T.J.; Duchateau, R.Angew.Chem., Int.Ed.2008, 47, 5816. doi: 10.1002/anie.v47:31
38. [38]
  Bollmann, A.; Blann, K.; Dixon, J.T.; Hess, F.M.; Killian, E.; Maumela, H.; McGuinness, D.S.; Morgan, D.H.; Neveling, A.; Otto, S.; Overett, M.; Slawin, A.M.Z.; Wasserscheid, P.; Kuhlmann, S.J.Am.Chem.Soc.2004, 126, 14712. doi: 10.1021/ja045602n
39. [39]
  Overett, M.J.; Blann, K.; Bollmann, A.; Dixon, J.T.; Haasbroek, D.; Killian, E.; Maumela, H.; McGuinness, D.S.; Morgan, D.H.J.Am.Chem.Soc.2005, 127, 10723. doi: 10.1021/ja052327b
40. [40]
  Blok, A.N.; Budzelaar, P.H.; Gal, A.W.Organometallics 2003, 22, 2564. doi: 10.1021/om030049o
41. [41]
  Britovsek, G.J.; McGuinness, D.S.; Wierenga, T.S.; Young, C.T.ACS Catal.2015, 5, 4152. doi: 10.1021/acscatal.5b00989
42. [42]
  Young, J.F.; Yap, G.Theopold, K H.In INOR 554-Reactivity of Chromium (Ⅱ) Bimetallocycles and Their Role in Ethylene Trimerization, Abstracts of Papers of the 234th ACS National Meeting, American Chemical Society, America, 2007, p.234.
43. [43]
  Peitz, S.; Aluri, B.R.; Peulecke, N.; Müller, B.H.; Wöhl, A.; Müller, W.; Al-Hazmi, M.H.; Mosa, F.M.; Rosenthal, U.Chem.Eur.J.2010, 16, 7670. doi: 10.1002/chem.201000750
44. [44]
  Breslow, D.S.; Newburg, N.R.J.Am.Chem.Soc.1957, 79, 5072.
45. [45]
  Long, W.P.; Breslow, D.S.J.Am.Chem.Soc.1960, 82, 1953. doi: 10.1021/ja01493a029
46. [46]
  Lee, P.Y.; Liang, L.C.Inorg.Chem.2009, 48, 5480. doi: 10.1021/ic802030d
47. [47]
  Long, W.P.J.Am.Chem.Soc.1959, 81, 5312. doi: 10.1021/ja01529a017
48. [48]
  Chien, J.C.J.Am.Chem.Soc.1959, 81, 86. doi: 10.1021/ja01510a019
49. [49]
  Zefirova, A.K.; Shilov, A.E.Dokl.Akad.Nauk SSSR 1961, 136, 599.
50. [50]
  Dyachkovskii, F.S.; Shilova, A.K.; Shilov, A.E.J.Polym.Sci., Part C:Polym.Symp.1967, 16, 2333.
51. [51]
  Jabri, A.; Crewdson, P.; Gambarotta, S.; Korobkov, I.; Duchateau, R.Organometallics 2006, 25, 715. doi: 10.1021/om050886l
52. [52]
  McGuinness, D.S.; Wasserscheid, P.; Keim, W.; Morgan, D.; Dixon, J.T.; Bollmann, A.; Maumela, H.; Hess, F.; Englert, U.J.Am.Chem.Soc.2003, 125, 5272. doi: 10.1021/ja034752f
53. [53]
  McGuinness, D.S.; Brown, D.B.; Tooze, R.P.; Hess, F.M.; Dixon, J.T.; Slawin, A.M.Organometallics 2006, 25, 3605. doi: 10.1021/om0601091
54. [54]
  Temple, C.; Jabri, A.; Crewdson, P.; Gambarotta, S.; Korobkov, I.; Duchateau, R.Angew.Chem.2006, 118, 7208. doi: 10.1002/(ISSN)1521-3757
55. [55]
  Zhang, J.; Li, A.; Hor, T.A.Organometallics 2009, 28, 2935. doi: 10.1021/om9002347
56. [56]
  Yoshida, T.; Yamamoto, T.; Okada, H.; Murakita, H.US 0035029, 2002[Chem.Abstr.2002, 136, 249387].
57. [57]
  McGuinness, D.S.; Overett, M.; Tooze, R.P.; Blann, K.; Dixon, J.T.; Slawin, A.M.Organometallics 2007, 26, 1108. doi: 10.1021/om060906z
58. [58]
  Deckers, P.J.; van der Linden, A.J.; Meetsma, A.; Hessen, B.Eur.J.Inorg.Chem.2000, 5, 929.
59. [59]
  Jabri, A.; Mason, C.B.; Sim, Y.; Gambarotta, S.; Burchell, T.J.; Duchateau, R.Angew.Chem., Int.Ed.2008, 47, 9717. doi: 10.1002/anie.v47:50
60. [60]
  Vidyaratne, I.; Nikiforov, G.B.; Gorelsky, S.I.; Gambarotta, S.; Duchateau, R.; Korobkov, I.Angew.Chem., Int.Ed.2009, 48, 6552. doi: 10.1002/anie.v48:35
61. [61]
  Reagan, W.K.EP 0417477, 1991[Chem.Abstr.1991, 115, 93172].
62. [62]
  Evans, D.F.J.Chem.Soc.1959, 2003. doi: 10.1039/jr9590002003
63. [63]
  Rucklidge, A.J.; McGuinness, D.S.; Tooze, R.P.; Slawin, A.M.; Pelletier, J.D.; Hanton, M.J.; Webb, P.B.Organometallics 2007, 26, 2782. doi: 10.1021/om0701975
64. [64]
  Brückner, A.; Jabor, J.K.; McConnell, A.E.; Webb, P.B.Organometallics 2008, 27, 3849. doi: 10.1021/om800316m
65. [65]
  Skobelev, I.Y.; Panchenko, V.N.; Lyakin, O.Y.; Bryliakov, K.P.; Zakharov, V.A.; Talsi, E.P.Organometallics 2010, 29, 2943. doi: 10.1021/om100215t
66. [66]
  Freeman, J.W.; Buster, J.L.; Knudsen, R.D.US 5856257, 1999[Chem.Abstr.1999, 130, 95984].
67. [67]
  Rabeah, J.; Bauer, M.; Baumann, W.; McConnell, A.E.; Gabrielli, W.F.; Webb, P.B.; Selent, D.; Bruckner, A.ACS Catal.2012, 3, 95.
68. [68]
  Weckhuysen, B.M.; Schoonheydt, R.A.; Jehng, J.M.; Wachs, I.E.; Cho, S.J.; Ryoo, R.; Kijlstra, S.; Poels, E.J.Chem.Soc., Faraday Trans.1995, 91, 3245. doi: 10.1039/FT9959103245
69. [69]
  Monillas, W.H.; Yap, G.; Theopold, K.H.Angew.Chem., Int.Ed.2007, 46, 6692. doi: 10.1002/(ISSN)1521-3773
70. [70]
  Poli, R.; Harvey, J.N.Chem.Soc.Rev.2003, 32, 1. doi: 10.1039/b200675h
71. [71]
  Köhn, R.D.Angew.Chem., Int.Ed.2008, 47, 245. doi: 10.1002/(ISSN)1521-3773
72. [72]
  Bhaduri, S.; Mukhopadhyay, S.; Kulkarni, S.A.J.Organomet.Chem.2009, 694, 1297. doi: 10.1016/j.jorganchem.2008.12.012
73. [73]
  Janse van Rensburg, W.; van den Berg, J.A.; Steynberg, P.J.Organometallics 2007, 26, 1000. doi: 10.1021/om060890c
74. [74]
  McGuinness, D.S.; Chan, B.; Britovsek, G.J.; Yates, B.F.Aust.J.Chem.2014, 67, 1481. doi: 10.1071/CH14436
75. [75]
  Tang, S.Y.; Liu, Z,; Zhan, X.W.; Cheng, R.H.; He, X.L.; Liu, B.P.J.Chem.Eng.2014, 65, 131(in Chinese).
76. [76]
  Mason, M.R.; Smith, J.M.; Bott, S.G.; Barron, A.R.J.Am.Chem.Soc.1993, 115, 4971. doi: 10.1021/ja00065a005
77. [77]
  Harlan, C.J.; Mason, M.R.; Barron, A.R.Organometallics 1994, 13, 2957. doi: 10.1021/om00020a011
78. [78]
  Babushkin, D.E.; Semikolenova, N.V.; Panchenko, V.N.; Sobolev, A.P.; Zakharov, V.A.; Talsi, E.P.Macromol.Chem.Phys.1997, 198, 3845. doi: 10.1002/macp.1997.021981206
79. [79]
  Zakharov, I.I.; Zakharov, V.A.Macromol.Theory Simul.2001, 10, 108. doi: 10.1002/(ISSN)1521-3919
80. [80]
  Pasha, F.A.; Basset, J.M.; Toulhoat, H.; de Bruin, T.Organometallics 2015, 34, 426. doi: 10.1021/om5008874
81. [81]
  Grubbs, R.H.; Coates, G.W.Acc.Chem.Res.1996, 29, 85. doi: 10.1021/ar9501683
82. [82]
  Harvey, J.N.; Poli, R.; Smith, K.M.Coord.Chem.Rev.2003, 238, 347.
83. [83]
  Salomon, O.; Reiher, M.; Hess, B.A.J.Chem.Phys.2002, 117, 4729. doi: 10.1063/1.1493179
84. [84]
  Reiher, M.; Salomon, O.; Hess, B.A.Theor.Chim.Acta 2001, 107, 48. doi: 10.1007/s00214-001-0300-3
85. [85]
  Tomov, A.K.; Chirinos, J.J.; Jones, D.J.; Long, R.J.; Gibson, V.C.J.Am.Chem.Soc.2005, 127, 10166. doi: 10.1021/ja051523f
86. [86]
  Tomov, A.K.; Chirinos, J.J.; Long, R.J.; Gibson, V.C.; Elsegood, M.R.J.Am.Chem.Soc.2006, 128, 7704. doi: 10.1021/ja0615369
87. [87]
  Blann, K.; Bollmann, A.; de Bod, H.; Dixon, J.T.; Killian, E.; Nongodlwana, P.; Maumela, M.C.; Maumela, H.; McConnell, A.E.; Morgan, D.H.; Overett, M.J.; Prétoriusa, M.; Kuhlmannb, S.; Wasserscheidb, P.J.Catal.2007, 249, 244. doi: 10.1016/j.jcat.2007.04.009
88. [88]
  Overett, M.J.; Blann, K.; Bollmann, A.; de Villiers, R.; Dixon, J.T.; Killian, E.; Maumela, M.C.; Maumela, H.McGuineess, D.S.; Morgan, D.H.; Rucklidge, A.; Slawin, A.M.Z.J.Mol.Catal.A:Chem.2008, 283, 114. doi: 10.1016/j.molcata.2007.11.036
89. [89]
  Jiang, T.; Liu, X.Y.; Ning, Y.N.; Chen, H.X.; Luo, M.J.; Wang, L.B.; Huang, Z.J.Catal.Commun.2007, 8, 1145. doi: 10.1016/j.catcom.2006.10.032
90. [90]
  McGuinness, D.S.; Rucklidge, A.J.; Tooze, R.P.; Slawin, A.M.Organometallics 2007, 26, 2561. doi: 10.1021/om070029c
91. [91]
  Chen, H.X.; Liu, X.Y.; Hu, W.B.; Ning, Y.N.; Jiang, T.J.Mol.Catal.A:Chem.2007, 270, 273. doi: 10.1016/j.molcata.2007.02.013
92. [92]
  Kuhlmann, S.; Blann, K.; Bollmann, A.; Dixon, J.T.; Killian, E.; Maumela, M.C.; Maumela, H.; Morgan, D.H.; Prétoriusb, M.; Taccardia, N.; Wasserscheid, P.J.Catal.2007, 245, 279. doi: 10.1016/j.jcat.2006.10.020
93. [93]
  Jiang, T.; Ning, Y.N.; Zhang, B.J.; Li, J.Z.; Wang, G.; Yi, J.J.; Huang, Q.J.Mol.Catal.A:Chem.2006, 259, 161. doi: 10.1016/j.molcata.2006.06.026
94. [94]
  Killian, E.; Blann, K.; Bollmann, A.; Dixon, J.T.; Kuhlmann, S.; Maumela, M.C.; Maumela, H.; Morgan, D.H.; Nongodlwanaa, P.; Overetta, M.J.; Pretoriusa, M.; Höfenerb, K.; Wasserscheidb, P.J.Mol.Catal.A:Chem.2007, 270, 214. doi: 10.1016/j.molcata.2007.01.046
95. [95]
  Jiang, T.; Zhang, S.; Jiang, X.L.; Yang, C.F.; Niu, B.; Ning, Y.N.J.Mol.Catal.A:Chem.2008, 279, 90. doi: 10.1016/j.molcata.2007.10.009
96. [96]
  Kuhlmann, S.; Dixon, J.T.; Haumann, M.; Morgan, D.H.; Ofili, J.; Spuhl, O.; Taccardi, N.; Wasserscheid, P.Adv.Synth.Catal.2006, 348, 1200. doi: 10.1002/(ISSN)1615-4169
97. [97]
  Overett, M.J.; Blann, K.; Bollmann, A.; Dixon, J.T.; Hess, F.; Killian, E.; Maumela, H.; Morgan, D.H.; Neveling, A.; Otto S.Chem.Commun.2005, 5, 622.
98. [98]
  Mao, G.L.; Ning, Y.N.; Hu, W.B.; Li, S.M.; Song, X.F.; Niu, B.; Jiang, T.Chin.Sci.Bull.2008, 53, 3511.
99. [99]
  Aluri, B.R.; Peulecke, N.; Müller, B.H.; Peitz, S.; Spannenberg, A.; Hapke, M.; Rosenthal, U.Organometallics 2010, 29, 226. doi: 10.1021/om900925b
1. [1]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
2. [2]
  Zuozhong Liang , Lingling Wei , Yiwen Cao , Yunhan Wei , Haimei Shi , Haoquan Zheng , Shengli Gao . Exploring the Development of Undergraduate Scientific Research Ability in Basic Course Instruction: A Case Study of Alkali and Alkaline Earth Metal Complexes in Inorganic Chemistry. University Chemistry, 2024, 39(7): 247-263. doi: 10.3866/PKU.DXHX202310103
3. [3]
  Peng YUE , Liyao SHI , Jinglei CUI , Huirong ZHANG , Yanxia GUO . Effects of Ce and Mn promoters on the selective oxidation of ammonia over V₂O₅/TiO₂ catalyst. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 293-307. doi: 10.11862/CJIC.20240210
4. [4]
  Shuang Yang , Qun Wang , Caiqin Miao , Ziqi Geng , Xinran Li , Yang Li , Xiaohong Wu . Ideological and Political Education Design for Research-Oriented Experimental Course of Highly Efficient Hydrogen Production from Water Electrolysis in Aerospace Perspective. University Chemistry, 2024, 39(11): 269-277. doi: 10.12461/PKU.DXHX202403044
5. [5]
  Yu Wang , Haiyang Shi , Zihan Chen , Feng Chen , Ping Wang , Xuefei Wang . 具有富电子Pt^δ^-壳层的空心AgPt@Pt核壳催化剂：提升光催化H₂O₂生成选择性与活性. Acta Physico-Chimica Sinica, 2025, 41(7): 100081-. doi: 10.1016/j.actphy.2025.100081
6. [6]
  Xuejie Wang , Guoqing Cui , Congkai Wang , Yang Yang , Guiyuan Jiang , Chunming Xu . 碳基催化剂催化有机液体氢载体脱氢研究进展. Acta Physico-Chimica Sinica, 2025, 41(5): 100044-. doi: 10.1016/j.actphy.2024.100044
7. [7]
  .
  CCS Chemistry | 超分子活化底物为自由基促进高效选择性光催化氧化
  . CCS Chemistry, 2025, 7(10.31635/ccschem.025.202405229): -.
8. [8]
  Fangxuan Liu , Ziyan Liu , Guowei Zhou , Tingting Gao , Wenyu Liu , Bin Sun . Hollow structured photocatalysts. Acta Physico-Chimica Sinica, 2025, 41(7): 100071-. doi: 10.1016/j.actphy.2025.100071
9. [9]
  Xilin Zhao , Xingyu Tu , Zongxuan Li , Rui Dong , Bo Jiang , Zhiwei Miao . Research Progress in Enantioselective Synthesis of Axial Chiral Compounds. University Chemistry, 2024, 39(11): 158-173. doi: 10.12461/PKU.DXHX202403106
10. [10]
  Zhiquan Zhang , Baker Rhimi , Zheyang Liu , Min Zhou , Guowei Deng , Wei Wei , Liang Mao , Huaming Li , Zhifeng Jiang . Insights into the Development of Copper-based Photocatalysts for CO₂ Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2406029-. doi: 10.3866/PKU.WHXB202406029
11. [11]
  Xue Liu , Lipeng Wang , Luling Li , Kai Wang , Wenju Liu , Biao Hu , Daofan Cao , Fenghao Jiang , Junguo Li , Ke Liu . Cu基和Pt基甲醇水蒸气重整制氢催化剂研究进展. Acta Physico-Chimica Sinica, 2025, 41(5): 100049-. doi: 10.1016/j.actphy.2025.100049
12. [12]
  Shihui Shi , Haoyu Li , Shaojie Han , Yifan Yao , Siqi Liu . Regioselectively Synthesis of Halogenated Arenes via Self-Assembly and Synergistic Catalysis Strategy. University Chemistry, 2024, 39(5): 336-344. doi: 10.3866/PKU.DXHX202312002
13. [13]
  Bing WEI , Jianfan ZHANG , Zhe CHEN . Research progress in fine tuning of bimetallic nanocatalysts for electrocatalytic carbon dioxide reduction. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 425-439. doi: 10.11862/CJIC.20240201
14. [14]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
15. [15]
  Qiangqiang SUN , Pengcheng ZHAO , Ruoyu WU , Baoyue CAO . Multistage microporous bifunctional catalyst constructed by P-doped nickel-based sulfide ultra-thin nanosheets for energy-efficient hydrogen production from water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1151-1161. doi: 10.11862/CJIC.20230454
16. [16]
  Yanan Liu , Yufei He , Dianqing Li . Preparation of Highly Dispersed LDHs-based Catalysts and Testing of Nitro Compound Reduction Performance: A Comprehensive Chemical Experiment for Research Transformation. University Chemistry, 2024, 39(8): 306-313. doi: 10.3866/PKU.DXHX202401081
17. [17]
  Jiahui YU , Jixian DONG , Yutong ZHAO , Fuping ZHAO , Bo GE , Xipeng PU , Dafeng ZHANG . The morphology control and full-spectrum photodegradation tetracycline performance of microwave-hydrothermal synthesized BiVO₄:Yb³⁺,Er³⁺ photocatalyst. Journal of Fuel Chemistry and Technology, 2025, 53(3): 348-359. doi: 10.1016/S1872-5813(24)60514-1
18. [18]
  Lewang Yuan , Yaoyao Peng , Zong-Jie Guan , Yu Fang . 二维共价有机框架作为光催化剂在有机合成中的研究进展. Acta Physico-Chimica Sinica, 2025, 41(8): 100086-. doi: 10.1016/j.actphy.2025.100086
19. [19]
  Tingyu Zhu , Hui Zhang , Wenwei Zhang . Exploration and Practice of Ideological and Political Education in the Course of Experiments on Chemical Functional Molecules: Synthesis and Catalytic Performance Study of Chiral Mn(III)Cl-Salen Complex. University Chemistry, 2024, 39(4): 75-80. doi: 10.3866/PKU.DXHX202311011
20. [20]
  Ke QIAO , Yanlin LI , Shengli HUANG , Guoyu YANG . Advancements in asymmetric catalysis employing chiral iridium (ruthenium) complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2091-2104. doi: 10.11862/CJIC.20240265

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(2517)
HTML views(710)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142