Citation: Hou Shuhua, Qu Zhongguo, Zhong Keli, Bian Yanjiang, Tang Lijun. Synthesis of a Novel Benzothiazole-Rhodamine Derivative and Its Selective Detection of Fe³⁺, Al³⁺ and Cr³⁺[J]. Chinese Journal of Organic Chemistry, ;2016, 36(4): 768-773. doi: 10.6023/cjoc201512041 shu

Synthesis of a Novel Benzothiazole-Rhodamine Derivative and Its Selective Detection of Fe³⁺, Al³⁺ and Cr³⁺

1.
Department of Chemistry, Bohai University, Jinzhou 121013

Corresponding author: Tang Lijun,
Received Date: 26 December 2015
Available Online: 2 February 2016
Fund Project: 辽宁省高等学校优秀人才支持计划(No.LR2015001)资助项目. (No.LR2015001)

A novel rhodamine-based probe L was synthesized from rhodamine B through "click chemistry". It showed that probe L acted as a naked-eye and "turn on" fluorescent probe for Fe³⁺, Al³⁺ and Cr³⁺ recognition.L is highly selective to trivalent ions (Fe³⁺, Al³⁺ and Cr³⁺) over other monovalent or divalent ions in CH₃OH. Detection limits of probe L for Fe³⁺, Cr³⁺and Al³⁺ are 9.7×10^-5, 6.9×10^-5 and 1.4×10^-4 mol/L, respectively, which could make it potentially applicable in Fe³⁺, Cr³⁺ and Al³⁺ detection.
- rhodamine,
- benzothiazole,
- click chemistry
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Synthesis of a Novel Benzothiazole-Rhodamine Derivative and Its Selective Detection of Fe3+, Al3+ and Cr3+

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通讯作者: 陈斌, bchen63@163.com

Synthesis of a Novel Benzothiazole-Rhodamine Derivative and Its Selective Detection of Fe³⁺, Al³⁺ and Cr³⁺