Citation: Zhang Junlin, Xiao Chuan, Zhai Lianjie, Wang Xijie, Bi Fuqiang, Wang Bozhou. Synthesis and Properties of the Fused Aza-polynitrocyclic Compounds[J]. Chinese Journal of Organic Chemistry, ;2016, 36(6): 1197-1207. doi: 10.6023/cjoc201512024 shu

Synthesis and Properties of the Fused Aza-polynitrocyclic Compounds

1.
Xi'an Modern Chemistry Research Instritute, Xi'an 710065

Corresponding author: Bi Fuqiang, bifuqiang@gmail.com Wang Bozhou, wbz600@163.com
Received Date: 19 December 2015
Revised Date: 7 January 2016

Fund Project: Project supported by the National Natural Science Foundation of China No. 21503162

Figures(18)

Fused aza-polycyclic structures play an important role in the synthesis of energetic compounds and the presence of NNO₂ groups renders them a rich source of energy. Currently, fused aza-polynitrocyclic compounds have gained considerable prominence as novel energetic compounds. This review focuses on the synthesis of various ring skeletons of the aza-bicyclic, aza-polycyclic and aza-propellane-derivatized energetic compounds as well as the studies of N-nitration, physicochemistry and detonation properties. The synthesis of pentaaza[3.3.3]propellane and hexaaza[3.3.3]propellane is highlighted and N-nitration explorations of these high-strained unstable skeletons are discussed in details.
- energetic compounds,
- fused aza-polycyclic structure,
- synthesis,
- N-nitration,
- properties
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