Citation: Wang Zhihui, Zhang Zhenfeng, Liu Yangang, Zhang Wanbin. Development of the Asymmetric Hydrogenation of Enol Esters[J]. Chinese Journal of Organic Chemistry, ;2016, 36(3): 447-459. doi: 10.6023/cjoc201512009 shu

Development of the Asymmetric Hydrogenation of Enol Esters

Wang Zhihui ^a ,
Zhang Zhenfeng ^a,*,, ,
Liu Yangang ^a ,
Zhang Wanbin ^a,b,*,,

a.
School of Pharmacy, Shanghai Jiao Tong University, Shanghai 200240
b.
School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai 200240

Corresponding author: Zhang Zhenfeng, Zhang Wanbin, wanbin@sjtu.edu.cn
Received Date: 7 December 2015
Revised Date: 6 January 2016

Fund Project: the Science and Technology Commission of Shanghai Municipality 14XD1402300the National Natural Science Foundation of China 21572131

Figures(10)

Chiral alcohols are an important class of compounds and possess a broad array of applications, thus their asymmetric preparation is an important area of research in the field of organic synthesis. Amongst methodologies for the preparation of such compounds, catalytic asymmetric hydrogenation has gained widespread interest due to its efficiency, environmentally friendliness and economic advantages, and is gradually becoming a technology with great potential for the industrial preparation of chiral alcohols. This review provides the first overview for the catalytic asymmetric hydrogenation of enol esters for the synthesis of chiral alcohols. A comprehensive and up-to-date introduction are given for a number of different substrates. A thorough analysis is provided concerning the advantages and disadvantages of different chiral ligands and their transition-metal complexes. Finally, a brief discussion relating to developments and potential areas of further research concerning new substrates, new ligands and new catalytic metals, is presented.
- enol esters,
- chiral alcohols,
- asymmetric hydrogenation,
- Ru-catalyzed,
- Rh-catalyzed
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