Citation: Miao Qun, Sun Huailin. Recent Progresses in the Chemistry of Münchnones[J]. Chinese Journal of Organic Chemistry, ;2016, 36(5): 913-926. doi: 10.6023/cjoc201511047 shu

Recent Progresses in the Chemistry of Münchnones

Miao Qun ,
Sun Huailin ^*,,

1.
State Key Laboratory of Elemento-Organic Chemistry, Collaborative Innovation Center of Chemical Science and Engineering Tianjin, Department of Chemistry, Nankai University, Tianjin 30071

Corresponding author: Sun Huailin, sunhl@nankai.edu.cn
Received Date: 25 November 2015
Revised Date: 21 December 2015

Fund Project: and the Natural Sciences Foundation of Tianjin City No. 08JCZDJC21600Project supported by the National Natural Science Foundation of China No. 20834002

Figures(27)

Münchnones are mesoionic five-membered heterocycles, which play an important role in heterocycles as well as in organic chemistry. Since they were discovered by Huisgen in 1964, there has been growing interest in syntheses, properties and application of münchnones. One of the most significant properties of münchnones is that they can undergo cycloaddition reactions to unsaturated bonds as 1,3-dipoles. This reaction has become an important method for the synthesis of pyrroles and other heterocycles. Recently, remarkable progresses have been achieved in the synthesis of münchnones by means of organo-metallic reactions, the new reactive properties of münchnones have also been explored, and the application of münchnones in organic synthesis has been widely reported. In this review, these recent progresses in the chemistry of münchnone are summarized.
- münchones,
- mesoionic compounds,
- dipolar cycloaddition,
- heterocycles
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