Citation: Wang Liang, Li Zhana, Wan Kang, Qu Xinga, Hu Siqian, Wang Feng. Progress in Diazo Compounds Mediated Transition-Metal-Catalyzed C—H Alkylation[J]. Chinese Journal of Organic Chemistry, ;2016, 36(5): 889-912. doi: 10.6023/cjoc201511017 shu

Progress in Diazo Compounds Mediated Transition-Metal-Catalyzed C—H Alkylation

Wang Liang ^a ,
Li Zhana ^a ,
Wan Kang ^a ,
Qu Xinga ^a ,
Hu Siqian ^a,*,, ,
Wang Feng ^b,*,,

a.
Key Laboratory of Optoelectronic Chemical Materials and Devices of Ministry of Education, School of Chemical and Environmental Engineering, Jianghan University, Wuhan 430056
b.
College of Chemistry and Materials Science, Hubei Engineering University, Xiaogan 432000

Corresponding author: Hu Siqian, hbeukj@126.com Wang Feng, wangliang@jhun.edu.cn
Received Date: 6 November 2015
Revised Date: 10 January 2016

Fund Project: Project supported by the National Natural Science Foundation of China No. 21302064and the Scientific Research Project of Hubei Provincial Department of Education No. B2015231

Figures(31)

Diazo compounds had been widely employed as a class of environment friendly and highly efficient coupling reagents in transition-metal-catalyzed C—H bonds insertion reactions. Recently, C—H alkylation of various arenes and heteroarenes has been achieved enormous successes using diazo compounds as the alkylation reagents under a new catalytic model. The recent progress in diazo compounds mediated transition-metal-catalyzed C—H alkylation and tandem C—H alkylation/cyclization is reviewed, including reaction mechanism and synthetic applications. Furthermore, the prospects of this reaction are also discussed.
- diazo compounds,
- transition-metal-catalysis,
- C—H activation,
- alkyaltion
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