Citation: Xie Yangxi, Li Fangyi, Zhao Changgui, Wang Jian. N-Heterocyclic Carbene Catalyzed and N-Fluorobenzenesulfonimide Mediated Oxidative Synthesis of Perester and Amide[J]. Chinese Journal of Organic Chemistry, ;2015, 36(1): 105-112. doi: 10.6023/cjoc201511013 shu

N-Heterocyclic Carbene Catalyzed and N-Fluorobenzenesulfonimide Mediated Oxidative Synthesis of Perester and Amide

1.
School of Pharmaceutical Sciences, Tsinghua University, Beijing 100084

Corresponding author: Wang Jian, wangjian2012@tsinghua.edu.cn
Received Date: 7 November 2015
Revised Date: 24 November 2015

Fund Project:

Figures(2)

The first study of oxidative synthesis of simple tert-butyl peresters and amides enabled by N-heterocyclic carbene-catalysis using N-fluorobenzenesulfonimide (NFSI) as oxidant is described. The reaction proceeds with green, high yield, board substrate scope and room temperature.
- N-heterocyclic carbene,
- N-fluorobenzenesulfonimide (NFSI),
- tert-butyl perester
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