Citation: Zhou Wenjun, Wang Dan, Zhang Xiazhong, Zeng Bin. Preparation and Catalytic Properties of a Novel Bamboo Fiber Supported-Palladium Catalyst (Fiber-Pd)[J]. Chinese Journal of Organic Chemistry, ;2016, 36(6): 1412-1418. doi: 10.6023/cjoc201510037 shu

Preparation and Catalytic Properties of a Novel Bamboo Fiber Supported-Palladium Catalyst (Fiber-Pd)

Zhou Wenjun ^a,b ,
Wang Dan ^a ,
Zhang Xiazhong ^a,b,*,, ,
Zeng Bin ^a

a.
College of Chemistry and Chemical Engineering, Neijiang Normal University, Neijiang 641112
b.
Key Laboratory of Fruit Waste Treatment and Resource Recycling of the Sichuan Provincial College, Sichuan 641112

Corresponding author: Zhang Xiazhong, chemzhwj@126.com
Received Date: 29 October 2015
Revised Date: 30 January 2016

Fund Project: and the Startup Foundation of Ph. D. Scientific Research of Neijiang Normal University No. 2012B05Project supported by the Sichuan Province Education Office Fostering Projects No. 15CZ0026the Youth Found of Sichuan Province Education Office Nos. 12ZB074, 13ZB0002, 11ZB024

Figures(5)

A novel bamboo fiber supported palladium (Fiber-Pd) catalyst was prepared with diphenylphosphinite fiber and palladium dichloride in ethanol. The as-prepared Fiber-Pd catalyst was characterized by X-ray photoelectron spectrometer (XPS), X-ray diffraction (XRD), thermogravimetric analyses (TGA), inductively coupled plasma-atomic emission spectrometry (ICP-AES), and transmission electron microscopy (TEM). The catalyst was applied to the Suzuki cross-coupling reaction between sodium tetraarylborate and aryl halides. Excellent yields of the corresponding functionalized biaryls were obtained when the reaction was performed in the presence of NaHCO₃ as base in PEG 400/H₂O at 85 ℃ within a short reaction time. It is noteworthy that the present protocol is highly efficient as 4 equiv. aryl halides reacted with 1 equiv. sodium tetraarylborate cleanly to provide high yield of the cross-coupling products in short reaction time. The catalyst can be easily separated and recovered from the reaction mixture by filtration and reused. This process has significant features of short reaction time, broad substrate scopes, easy isolation of the product, and atom-efficient coupling under mild conditions in environmentally friendly media in air.
- bamboo fiber supported palladium,
- preparation,
- Suzuki reaction,
- sodium tetraphenylborate,
- aryl halide
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