Citation: Tan Nianyuan, Wang Penghui, Xu Xinhua, Gao Qingsong, Au Chaktong, Qiu Renhua. Efficient Synthesis of β-Amino Alcohols Promoted by Triphenylbismuth Bisperfluorooctanesulfonates[J]. Chinese Journal of Organic Chemistry, ;2016, 36(5): 1094-1098. doi: 10.6023/cjoc201510035 shu

Efficient Synthesis of β-Amino Alcohols Promoted by Triphenylbismuth Bisperfluorooctanesulfonates

Tan Nianyuan ^a ,
Wang Penghui ^b ,
Xu Xinhua ^b ,
Gao Qingsong ^c ,
Au Chaktong ^a,b,*,, ,
Qiu Renhua ^b,*,,

a.
College of Chemistry and Chemical Engineering, Hunan Institute of Engineering, Xiangtan 411104
b.
College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082
c.
Hubei Province Fibre Inspection Bureau, Wuhan 430061

Corresponding author: Au Chaktong, pctowl@hotmail.com Qiu Renhua, renhuaqiu@hnu.edu.cn
Received Date: 29 October 2015
Revised Date: 21 January 2016

Fund Project: the Natural Science Foundation of Hunan Province No.14JJ7027and the Key Project of Hunan Province Education Department No.15A041Projected support by the National Natural Science Foundation of China No.21373003

Figures(2)

In this paper, a novel air-stable triphenylbismuth bisperfluorooctanesulfonate was synthesized by treatment of moisture-sensitive triphenylbismuth dichloride with silver bisperfluorooctanesulfonate in anhydrous CH₂Cl₂ at room temperature. Its catalytic assessment results show that the reactions of arylamine and epoxide proceed efficiently in the presence of triphenylbismuth bisperfluorooctanesulfonates 1(5.0 mol%) under solvent-free condition, affording β-amino alcohols in good to excellent yields. The yields of desired products do not reduce obviously after recycling for 4 times of catalyst 1. Hence, a convenient and efficient method for preparation of β-amino alcohols is provided.
- organobismuth,
- perfluorooctanesulfonate,
- Lewis acid,
- β-amino alcohol,
- solvent-free synthesis
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