Citation: Jian Zukai, Yang Yang, Lang Meidong, Li Yongjun. Atom Transfer Radical Polymerization of Secondary Amine Containing Methacrylate Monomer[J]. Chinese Journal of Organic Chemistry, ;2016, 36(2): 412-416. doi: 10.6023/cjoc201509039 shu

Atom Transfer Radical Polymerization of Secondary Amine Containing Methacrylate Monomer

Jian Zukai ^a ,
Yang Yang ^b ,
Lang Meidong ^a,, ,
Li Yongjun ^b,,

1.
a Key Laboratory for Ultrafine Materials of Ministry of Education, School of Materials Science and Engineering, East China University of Science and Technology, Shanghai 200237;
2.
b Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032

Corresponding author: Lang Meidong, Li Yongjun,
Received Date: 19 September 2015
Available Online: 16 October 2015
Fund Project: 国家自然科学基金(No. 21204098)资助项目 (No. 21204098)

Radical polymer poly(2,2,6,6-tetramethylpiperidinyloxy-4-yl methacrylate) (PTMA), a potential cathode materials, was prepared by radical polymerization of 2,2,6,6-tetramethylpiperidin-4-yl methacrylate (TMPM) containing secondary amine group, followed by oxidation into radical polymer. However, the living radical polymerization of TMPM was hindered by its secondary amine group. The optimized atom transfer radical polymerization condition for TMPM via screening various initiators and catalyst systems was reported, and poly(2,2,6,6-tetramethylpiperidin-4-yl methacrylate)s with different molecular weight were prepared.
- methacrylate,
- secondary amine,
- atom transfer radical polymerization
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